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Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences

Orientation

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Intermolecular Dynamics Of Condensed State: Study Of Temperature Effect On Anisotropy Relaxation By Vibration Spectroscopy, Bakhodir Eshchanov, Shavkat Otajonov, Jurat Gayipov, Dilafruz Xudoyberdiyeva, Sarvarbek Qurbanbayev Sep 2020

Intermolecular Dynamics Of Condensed State: Study Of Temperature Effect On Anisotropy Relaxation By Vibration Spectroscopy, Bakhodir Eshchanov, Shavkat Otajonov, Jurat Gayipov, Dilafruz Xudoyberdiyeva, Sarvarbek Qurbanbayev

Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences

As a result of the experimental study of the spectra of anisotropic scattering of light, a character of orientation movement of molecules in aromatic hydrocarbons has been analyzed. The obtained results have been interpreted from the viewpoint of a model of inhibited rotation and the contributions of the rotational and vibrational degrees of freedom to a molecule spectrum have been estimated. With increasing temperature of liquids under study and approaching a critical state, the rotational degrees of freedom "freeze", and the vibrational degrees have become more significant.