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Controlling The Optical Properties Of A Conjugated Co-Polymer Through Variation Of Backbone Isomerism And The Introduction Of Carbon Nanotubes, A. Dalton, J. Coleman, M. In Het Panhuis, B. Mccarthy, A. Drury, W. Blau, J. Nunzi, Hugh Byrne
Controlling The Optical Properties Of A Conjugated Co-Polymer Through Variation Of Backbone Isomerism And The Introduction Of Carbon Nanotubes, A. Dalton, J. Coleman, M. In Het Panhuis, B. Mccarthy, A. Drury, W. Blau, J. Nunzi, Hugh Byrne
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The need to control the formation of weakly emitting species in polymers such as aggregates and excimers, which are normally detrimental to device performance, is illustrated for the example of the polymer poly(m-phenylenevinylene-co-2,5-dioctyloxy-p-phenylenevinylene), using the model compound, 2,5-dioctyloxy-p-distyrylbenzene as a comparison. Two different methods, namely a Homer-Emmons polycondensation in dimethylformamide (DMF) and a Wittig polycondensation in dry toluene, have been used during synthesis resulting in a polymer with a predominantly trans-vinylene backbone and a polymer with a predominantly cis-vinylene backbone, respectively. Photoluminescence and absorption spectroscopy indicate that the polymer forms aggregate species in solution with spectra that are distinctly red-shifted …