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Wayne State University

2012

Antiferromagnetic, doping, magnetoelectric, multiferroic, phase transitions

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Effects Of Transition Metal Doping On Multiferroic Ordering In Ni3v2o8 And Fevo4, Akila Deeghayu Kumarasiri Jan 2012

Effects Of Transition Metal Doping On Multiferroic Ordering In Ni3v2o8 And Fevo4, Akila Deeghayu Kumarasiri

Wayne State University Dissertations

We have studied the effects of doping both non-magnetic and magnetic ions on the phase transitions and multiferroic ordering in two multiferroic oxides; Ni3V2O8 and FeVO4. Magnetic, dielectric, specific heat, polarization and AC susceptibility measurements were used to track changes in phase transition temperatures. We found that the two higher temperature magnetic transitions in Ni3V2O8; TH = 9.1 K and TL = 6.3 K are suppressed to lower temperatures with all transition metal dopants. For Zn doping, the rates of the suppression of both TH and TL with dopant fraction are consistent with simple site dilution for two-dimensional spin systems, …