Physics Commons^™

The Impact Of A Nuclear Disturbance On A Space-Based Quantum Network, Alexander Miloshevsky

Doctoral Dissertations

Quantum communications tap into the potential of quantum mechanics to go beyond the limitations of classical communications. Currently, the greatest challenge facing quantum networks is the limited transmission range of encoded quantum information. Space-based quantum networks offer a means to overcome this limitation, however the performance of such a network operating in harsh conditions is unknown. This dissertation analyzes the capabilities of a space-based quantum network operating in a nuclear disturbed environment. First, performance during normal operating conditions is presented using Gaussian beam modeling and atmospheric modeling to establish a baseline to compare against a perturbed environment. Then, the DEfense …

Laser-Induced Breakdown Spectroscopy And Plasmas Containing Cyanide, Christopher Matthew Helstern

Doctoral Dissertations

This dissertation focuses on laser-induced plasma of diatomic molecular cyanide. Optical breakdown plasma generation is produced by high-peak-power 1064 nm Q-switched nanosecond pulsed radiation. Laser-induced breakdown is performed on a 1:1 molar gas mixture of carbon dioxide and nitrogen held at a fixed pressure of 760 Torr, a 1:1 molar gas mixture of carbon dioxide and nitrogen held at a fixed pressure of 2069 Torr, and a flowing 1:1 molar gas mixture of carbon dioxide and nitrogen flowing at a rate of 100 mL per minute. Plasma shockwave measurements in laboratory air are shown to determine the shock front geometry …

Characterization Of A Digital Holography Diagnostic For In Situ Erosion Measurement Of Plasma-Facing Components In Fusion Devices, Cary Dean Smith

Doctoral Dissertations

Fusion energy devices, particularly tokamaks, face the challenge of interior surface damage occurring over time from the heat flux of the high-energy plasma they generate. The ability to monitor the rate of surface modification is therefore imperative, but to date no proven technique exists for real-time erosion measurement of planar regions of interest on plasma-facing components in fusion devices. In order to fill this diagnostic gap, a digital holography system has been established at ORNL [Oak Ridge National Laboratory] for the purpose of measuring the erosion effects of plasma-material interaction in situ.

The diagnostic has been designed with the …

Using Second Harmonic Generation To Study Gram-Positive Bacterial Membranes, Lindsey N. Miller

Doctoral Dissertations

Understanding how small-molecules, such as drugs, interact with bacterial membranes can quickly unravel into much more perplexing questions. No two bacterial species are alike, especially when comparing their membrane compositions which can even be altered by incorporating fatty acids from their surrounding environment into their lipid-membrane composition. To further complicate the comparison, discrete alterations in small-molecule structures can result in vastly different membrane-interaction outcomes, giving rise to the need for more "label-free" studies when analyzing drug mechanisms. The work presented in this dissertation highlights the benefits to using nonlinear spectroscopy and microscopy techniques for probing small-molecule interactions in living bacteria. …

Local Moments And Itinerant Electrons: Gaining New Insights Through Investigating Electronic And Dynamical Properties, Nicholas Steven Sirica

Doctoral Dissertations

Magnetic materials are often categorized in terms of either a purely local or a purely itinerant picture despite the fact that the vast majority actually fall within a spectrum that ranges between these two extremes. It is from such a starting point that this thesis aims at developing an understanding of how the complex interplay between local moments and itinerant electrons ultimately affects the electronic and dynamical properties. Such ideas are explored in greater detail using two materials as case studies: the chiral helimagnet Cr_1/3NbS₂ [Cr intercalated Niobium Disulfide] and YFe₂Ge₂ [Yttrium Iron Germanide] …

Symbiotic Plasmonic Nanomaterials: Synthesis And Properties, Abhinav Malasi

Doctoral Dissertations

Metal particles of the dimensions of the order of 1 to 100's of nanometers show unique properties that are not clearly evident in their bulk state. These nanoparticles are highly reactive and sensitive to the changes in the vicinity of the particle surface and hence find applications in the field of sensing of chemical and biological agents, catalysis, energy harvesting, data storage and many more. By synthesizing bimetallic nanoparticles, a single nanoparticle can show multifunctional characteristics. The focus of this thesis is to detail the synthesis and understand the properties of bimetallic nanomaterial systems that show interesting optical, chemical, and …

Measurements Of Methyl Radicals And Temperatures By Using Coherent Microwave Rayleigh Scattering From Resonance Enhanced Multiphoton Ionization, Yue Wu

Doctoral Dissertations

This thesis includes two main parts: (I) The CH₃[methyl radical] detection in methane/air flames and (II) the rotational temperature measurement of O₂[molecular oxygen] in a variety of environments by using coherent microwave Rayleigh scattering from resonance enhanced multiphoton ionization (Radar REMPI).

In first the part, from Chapter I to Chapter III, the methyl radical detection and quantitative measurements have been conducted in hydrocarbon flame with one-dimensional and two-dimensional spatial-resolved concentration distribution. Due to the proximity of the argon resonance state (4+1 REMPI by 332.5 nm) with the CH₃ state (2+1 REMPI by 333.6 nm), in …

Phase Dynamics Of Locset Control Methodology, Brendan Neschke

Masters Theses

Single-mode fiber amplifiers produce diffraction-limited beams very efficiently. Maximum beam intensity requires that an array of these amplifiers have their beams coherently combined at the target. Optical path differences and noise adversely affect beam quality. An existing closed loop phase control methodology, called the locking of optical coherence by single-detector electronic-frequency tagging (LOCSET), corrects phase errors in real time by electronically detecting path length differences and sending signals to lithium niobate phase adjusters. Broadening the line-width using “jitter” of the input signal can increase the output power of an individual amplifier by suppressing nonlinearity. The system dynamics of LOCSET are …

Understanding The Plasmonic Properties Of Metallic Nanostructures With Correlated Photon- And Electron-Driven Excitations, Vighter Ozezinimize Iberi

Doctoral Dissertations

The collective oscillation of the conduction band electrons in metal nanostructures, known as plasmons, can be used to manipulate light on length scales that are smaller than the diffraction limit of visible light. In this dissertation, a correlated approach is used to probe localized surface plasmon resonances (LSPRs) in metallic nanostructures, and their application to surface-enhanced spectroscopy. This correlated approach involves the measurement of LSPRs with dark-field optical microscopy (resonance-Rayleigh scattering), and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Structural parameters of the exact same nanostructures obtained from the STEM are subsequently used in performing fully …

Tracking Real-Time Nanoparticle Positions And Measuring Three-Dimensional Solution Flow With A Four-Focus Confocal Microscope, James Andrew Germann

Doctoral Dissertations

This dissertation presents the development of instrumentation for measuring the position of a single emitter within the sample volume of a confocal fluorescence microscope with sub-diffraction limited precision in three dimensions together with applications for determining solution flow and for tracking a fluorescent nanoparticle as it undergoes Brownian diffusion. The localization method is based on comparing photon counts from alternating excitation of the emitter by four laser beams, which are focused at slightly offset positions in a tetrahedral pattern within the confocal volume. Two experimental set-ups are constructed. In the first, the four beams are from a femtosecond laser, which …

Three-Dimensional Electrokinetic Trapping Of A Single Fluorescent Nanoparticle In Solution, Jason Keith King

Doctoral Dissertations

This dissertation presents the development of an instrument for effectively trapping a single fluorescent nanoparticle that is freely diffusing in solution in all three dimensions. The instrument is expected to have applications for studies of single nanoparticles or molecules for which prolonged observations are required, but without immobilization or proximity to a surface, which may alter behavior. The trapping technique depends on rapid three-dimensional position measurements of the nanoparticle with sub-micron precision, which are used for real-time control of induced electrokinetic motion, so as to counteract Brownian motion. While anti-Brownian electrokinetic trapping experiments in one and two dimensions have previously …

Femtosecond Laser Patterned Templates And Imprinted Polymer Structures, Deepak Rajput

Doctoral Dissertations

Femtosecond laser machining is a direct-write lithography technique by which user-defined patterns are efficiently and rapidly generated at the surface or within the bulk of transparent materials. When femtosecond laser machining is performed with tightly focused amplified pulses in single-pulse mode, transparent substrates like fused silica can be surface patterned with high aspect ratio (>10:1) and deep (>10 μm) nanoholes. The main objective behind this dissertation is to develop single-pulse amplified femtosecond laser machining into a novel technique for the production of fused silica templates with user-defined patterns made of high aspect ratio nanoholes. The size of the …

Morphology-Properties Studies In Laser Synthesized Nanostructured Materials, Nozomi Shirato

Doctoral Dissertations

Synthesis of well-defined nanostructures by pulsed laser melting is an interesting subject from both a funda- mental and technological point of view. In this thesis, the synthesis and functional properties of potentially useful materials were studied, such as tin dioxide nanostructured arrays, which have potential applications in hydrogen gas sensing, and ferromagnetic Co nanowire and nanomagnets, which are fundamentally im- portant towards understanding magnetism in the nanoscale. First, the formation of 1D periodic tin dioxide nanoarrays was investigated with the goal of forming nanowires for hydrogen sensing. Experimental obser- vations combined with theoretical modeling successfully explained the mechanisms of structure …

Water Ice Films In Cryogenic Vacuum Chambers, Jesse Michael Labello

Doctoral Dissertations

The space simulation chambers at Arnold Engineering Development Complex (AEDC) allow for the testing and calibration of seeker sensors in cryogenic, high vacuum environments. During operation of these chambers, contaminant films can form on the components in the chamber and disrupt operation. Although these contaminant films can be composed of many molecular species, depending on the species outgassed by warm chamber components and any leaks or virtual leaks (pockets of gas trapped within a vacuum chamber) that may be present, water vapor is most common, and it will be the focus of this dissertation. In this dissertation, some properties of …

Monte Carlo Simulations Of Single-Molecule Fluorescence Detection Experiments, William Neil Robinson

Doctoral Dissertations

Several Monte Carlo simulations of single-molecule fluorescence systems are developed to help evaluate and improve ongoing experiments. In the first simulation, trapping of a single molecule in a nanochannel is studied. Molecules move along the nanochannel by diffusion and electrokinetic flow. Single-molecule fluorescence signals excited by two spatially offset laser beams are detected and the direction of the flow is adjusted to try to equalize the signals and center the molecule between the beams. An algorithm is evaluated for trapping individual molecules in succession by rapidly reloading the trap after a molecule photobleaches or escapes. This is shown to be …

Quantitative Binocular Assessment Using Infrared Video Photoscreening, Lei Shi

Doctoral Dissertations

Photorefraction is a technique that has been used in the past two decades for pediatric vision screening. The technique uses a digital or photographic camera to capture the examinee‟s retinal reflex from a light source that is located near the camera‟s lens. It has the advantages of being objective, binocular and low cost, which make it a good candidate for pediatric screening when compared to other methods. Although many children have been screened using this technique in the U.S., its sensitivity and other disadvantages make it unacceptable for continued use. The Adaptive Photorefraction system (APS) was developed at the Center …

Digital Aperture Photometry Utilizing Growth Curves, William Chandler Overcast

Masters Theses

Point source extraction is critical to proper analysis of images containing point sources obtained by focal plane array cameras. Two popular methods of extracting the intensity of a point source are aperture photometry and point spread function fitting. Digital aperture photometry encompasses procedures utilized to extract the intensity of an imaged point source. It has been used by astronomers in various forms for calculating stellar brightness. It is also useful for doing analysis of data associated with other unresolved radiating objects. The various aperture photometry methods include the two-aperture method, aperture correction, and growth curve method.

The growth curve method …

High-Sensitivity Spectral Fluorescence Lifetime Imaging For Resolving Spectroscopically Overlapping Species, Justin Lee Crawford

Masters Theses

The capability to resolve the contributions from spectroscopically overlapping fluorophores has enabled significant breakthroughs in cellular imaging. However, commercial microscopes for this purpose use analog light detection with least squares curve-fitting analysis and improvements in sensitivity are needed. To this end, a microscope has been constructed with high throughput and single-photon detection capability. The fluorescence is separated through use of a prism spectrometer or a series of dichroic mirrors into four spectral bands and detected using four single-photon avalanche diode (SPAD) detectors, which provide high-quantum efficiency in the red spectral region. The detectors are connected to a time-correlated single photon …