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Full-Text Articles in Physics
Resonant Inelastic X-Ray Scattering Of Methyl Chloride At The Chlorine K Edge, L. El Khoury, Loic Journel, Renaud Guillemin, Stephane Carniato, Wayne C. Stolte, T. Marin, Dennis W. Lindle, Marc Simon
Resonant Inelastic X-Ray Scattering Of Methyl Chloride At The Chlorine K Edge, L. El Khoury, Loic Journel, Renaud Guillemin, Stephane Carniato, Wayne C. Stolte, T. Marin, Dennis W. Lindle, Marc Simon
Chemistry and Biochemistry Faculty Research
We present a combined experimental and theoretical study of isolated CH3Cl molecules using resonant inelastic x-ray scattering (RIXS). The high-resolution spectra allow extraction of information about nuclear dynamics in the core-excited molecule. Polarization-resolved RIXS spectra exhibit linear dichroism in the spin-orbit intensities, a result interpreted as due to chemical environment and singlet-triplet exchange in the molecular core levels. From analysis of the polarization-resolved data, Cl 2px, y and 2pz electronic populations can be determined.