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Full-Text Articles in Physics
Transverse And Longitudinal Thermal Diffusivity Measurements Of Polymer And Small Molecule Organic Semiconductors With Different Techniques, Maryam Shahi
Theses and Dissertations--Physics and Astronomy
The main thrust of this research was to develop new probes to measure thermal conductivities (κ) of small-molecule crystals, as well as polymer blends of organic semiconductors, both to screen these for possible applications, e.g. as thermoelectric power generators, and to gain an understanding of thermal transport in them. Emphasis has been on the crystals of “TIPS pentacene” [TIPS = 6,13 bis(triisopropylsilylethynyl), and free-standing films of PEDOT:PSS [poly(3,4-ethylenedioxythiophene) polystyrene sulfonate] for different electrochemical and thermoelectric applications. Separate techniques were used for in-plane and transverse thermal conductivities in which 𝜅𝜅 is determined indirectly from measurements of the thermal diffusivity (D ≡ …
Thermal Conductivities Of Organic Semiconductors, Yulong Yao
Thermal Conductivities Of Organic Semiconductors, Yulong Yao
Theses and Dissertations--Physics and Astronomy
Organic semiconductors have gained a lot of interest due to their ease of processing, low-cost and inherent mechanical flexibility. Although most of the research has been on their electronic and optical properties, knowledge of the thermal properties is important in the design of electronic devices as well. Our group has used ac-calorimetric techniques to measure both in-plane and transverse thermal conductivities of a variety of organic semiconductors including small-molecule crystals and polymer blends. For layered crystals composed of molecules with planar backbones and silylethynyl (or germylethynyl) sidegroups projecting between the layers, very high interplanar thermal conductivities have been observed, presumably …
The Development And Implementation Of Systems To Study The Physical Properites Of Tantalum Trisulfide And Small-Molecule Organic Semiconductors, Hao Zhang
Theses and Dissertations--Physics and Astronomy
The charge-density-wave (CDW) material orthorhombic tantalum trisulfide (TaS3) is a quasi-one dimensional material that forms long ribbon shaped crystals, and exhibits unique physical behavior. We have measured the dependence of the hysteretic voltage-induced torsional strain (VITS) in TaS3, which was first discovered by Pokrovskii et. al. in 2007, on temperature and applied torque. Our experimental results shows that the application of torque to the crystal could also change the VITS time constant, magnitude, and sign. This suggests that the VITS is a consequence of residual torsional strain originally present in the sample which twists the polarizations …