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Full-Text Articles in Physics
Use Of Raman Spectroscopy In The Investigation Of Debundling Of Single Walled Carbon Nanotubes, Elizabeth Gregan, Sinead Keogh, Theresa Hedderman, Gordon Chambers, Hugh Byrne
Use Of Raman Spectroscopy In The Investigation Of Debundling Of Single Walled Carbon Nanotubes, Elizabeth Gregan, Sinead Keogh, Theresa Hedderman, Gordon Chambers, Hugh Byrne
Conference papers
Samples of raw nanotubes are compared to those deposited from solutions to examine separation of nanotube bundles. Single wall nanotubes bundles produced by the arc-discharge and HiPco methods were solubilised in toluene, DMF and 1,2 dichloroethane. Resonant Raman spectroscopy was used to determine if debundling of the tubes sample occurred. The results showed some degree of debundling, best for the 1,2 dichloroethane solvent, which also shows long term solubility.
Interaction Of Carbon Nanotubes With Saccharides: A Possible Route To Biocompatible Composites, Alan Casey, Jonathan Moghal, Gerald Farrell, Hugh Byrne, Gordon Chambers
Interaction Of Carbon Nanotubes With Saccharides: A Possible Route To Biocompatible Composites, Alan Casey, Jonathan Moghal, Gerald Farrell, Hugh Byrne, Gordon Chambers
Conference papers
Inclusion complexes of saccharides and HiPco Carbon Nanotubes (HCNT) were formed, resulting in water soluble complexes. These complexes were then characterised using a variety of spectroscopic techniques. Raman spectroscopy was used to probe changes in the vibrational character of both the host and guest species and also to assess if any selectivity of tube diameter occurred. UV-Vis-NIR and circular dichroic spectroscopies were used to assess the effect of inclusion on the electronic properties of the tubes. Spectroscopic analysis of these species showed clear evidence of an intermolecular interaction between the host material and the HCNT.