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Structural, Electrical And Spectral Studies On Double Rare-Earth Orthoferrites La_{1-X}Nd_Xfeo_3, O.M. Hemeda, Mohsen Mohamed Barakat, D. M. Hemeda
Structural, Electrical And Spectral Studies On Double Rare-Earth Orthoferrites La_{1-X}Nd_Xfeo_3, O.M. Hemeda, Mohsen Mohamed Barakat, D. M. Hemeda
Turkish Journal of Physics
Samples of double rare-earth ferrite La_{1-x}Nd_xFeO_3 are synthesized by a high-temperature double sintering ceramic technique. X-ray diffraction shows that all compounds have an orthorhombic structure. The values of lattice parameter and the volume of the unit cell, changes with increasing Nd^{3+} content. The Goldschmidt tolerance factor decreases and goes far from unity with increasing Nd content. The samples containing Nd ions with x = 0.1, 0.2 and 0.3 have higher resistivity than that of LaFeO_{3}, but for x \ge 0.4 the resistivity decreases. The results indicate the presence of extrinsic semiconducting properties up to 100 °C above which the hopping …