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Full-Text Articles in Physics
Semi-Analytical Solutions For One - And Two-Dimensional Pellet Problems., Tim Marchant
Semi-Analytical Solutions For One - And Two-Dimensional Pellet Problems., Tim Marchant
Tim Marchant
The problem of heat and mass transfer within a porous catalytic pellet in which an irreversible first–order exothermic reaction occurs is a much–studied problem in chemical–reactor engineering. The system is described by two coupled reaction–diffusion equations for the temperature and the degree of reactant conversion. The Galerkin method is used to obtain a semi–analytical model for the pellet problem with both one– and two–dimensional slab geometries. This involves approximating the spatial structure of the temperature and reactant–conversion profiles in the pellet using trial functions. The semi–analytical model is obtained by averaging the governing partial differential equations. As the Arrhenius law …
Cubic Autocatalysis With Michaelis - Menten Kinetics: Semi-Analytical Solutions For The Reaction - Diffusion Cell, Tim Marchant
Cubic Autocatalysis With Michaelis - Menten Kinetics: Semi-Analytical Solutions For The Reaction - Diffusion Cell, Tim Marchant
Tim Marchant
Cubic-autocatalysis with Michaelis–Menten decay is considered in a one-dimensional reaction–diffusion cell. The boundaries of the reactor allow diffusion into the cell from external reservoirs, which contain fixed concentrations of the reactant and catalyst. The Galerkin method is used to obtain a semi-analytical model consisting of ordinary differential equations. This involves using trial functions to approximate the spatial structure of the reactant and autocatalyst concentrations in the reactor. The semi-analytical model is then obtained from the governing partial differential equations by averaging. The semi-analytical model allows steady-state concentration profiles and bifurcation diagrams to be obtained as the solution to sets of …