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Air Force Institute of Technology

2018

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Articles 1 - 30 of 37

Full-Text Articles in Physics

Electrical Characterization Of Crystalline Uo2, Tho2 And U0.71Th0.29O2, Christina L. Dugan Dec 2018

Electrical Characterization Of Crystalline Uo2, Tho2 And U0.71Th0.29O2, Christina L. Dugan

Theses and Dissertations

Uranium dioxide (UO2), thorium dioxide (ThO2), and UxTh1-xO2 alloys are characterized for suitability in uranium-based neutron detectors. ThO2 was studied for an envisioned UO2/ThO2 heterojunction. A U0.71Th0.29O2 alloy was studied because of its resistance to oxidation and potential use in surface passivation. The U0.71Th0.29O2 effective Debye temperature of 217± 24 K was measured using temperature-dependent x-ray photoemission spectroscopy (XPS). The specific heat capacity for the U0.71Th0.29O2 alloy was calculated from the Debye …


Kinetics Of Higher Lying Potassium States After Excitation Of The D2 Transition In The Presence Of Helium, Austin J. Wallerstein Dec 2018

Kinetics Of Higher Lying Potassium States After Excitation Of The D2 Transition In The Presence Of Helium, Austin J. Wallerstein

Theses and Dissertations

A kinetic model for the performance of a potassium Diode Pumped Alkali Laser (DPAL), including the role of higher lying states is developed to assess the impact on device efficiency and performance. A rate package for a nine level kinetic model including recommended rate parameters is solved under steady-state conditions. Energy pooling and far wing absorption populates higher lying states, with single photon and Penning ionization leading to modest potassium (K) dimer ion concentrations. The fraction of the population removed from the basic three levels associated with the standard model is less than 10% for all reasonable laser conditions, including …


Improving Detection Of Dim Targets: Optimization Of A Moment-Based Detection Algorithm, Shannon R. Young Dec 2018

Improving Detection Of Dim Targets: Optimization Of A Moment-Based Detection Algorithm, Shannon R. Young

Theses and Dissertations

Wide area motion imagery (WAMI) sensor technology is advancing rapidly. Increases in frame rates and detector array sizes have led to a dramatic increase in the volume of data that can be acquired. Without a corresponding increase in analytical manpower, much of these data remain underutilized. This creates a need for fast, automated, and robust methods for detecting dim, moving signals of interest. Current approaches fall into two categories: detect-before-track (DBT) and track-before-detect (TBD) methods. The DBT methods use thresholding to reduce the quantity of data to be processed, making real time implementation practical but at the cost of the …


Estimation Of Atmospheric Turbulence Using Differential Motion Of Extended Features In Time-Lapse Imagery, Santasri Bose-Pillai, Jack E. Mccrae, Christopher A. Rice, Ryan A. Wood, Conner E. Murphy, Steven T. Fiorino Oct 2018

Estimation Of Atmospheric Turbulence Using Differential Motion Of Extended Features In Time-Lapse Imagery, Santasri Bose-Pillai, Jack E. Mccrae, Christopher A. Rice, Ryan A. Wood, Conner E. Murphy, Steven T. Fiorino

Faculty Publications

We address the design, development, and testing of a pointer/tracker as a probe beam for the purpose of making high-speed, aero-optical measurements of the flow over a scaled beam director turret. The tracker uses retro-reflection of the probe beam off of a Reflexite annulus surrounding the turret. The constraints of the design required a near-total-commercial off the shelf system that could be quickly installed and removed in a rented aircraft. Baseline measurements of environmental vibrations are used to predict pointing performance; mitigation of line-of-sight jitter on the probe beam is achieved through passive isolation and the design of relay optics. …


Design And Optimization Of A 3-D Plasmonic Huygens Metasurface For Highly-Efficient Flat Optics, Bryan M. Adomanis Sep 2018

Design And Optimization Of A 3-D Plasmonic Huygens Metasurface For Highly-Efficient Flat Optics, Bryan M. Adomanis

Theses and Dissertations

For miniaturization of future USAF unmanned aerial and space systems to become feasible, accompanying sensor components of these systems must also be reduced in size, weight and power (SWaP). Metasurfaces can act as planar equivalents to bulk optics, and thus possess a high potential to meet these low-SWaP requirements. However, functional efficiencies of plasmonic metasurface architectures have been too low for practical application in the infrared (IR) regime. Huygens-like forward-scattering inclusions may provide a solution to this deficiency, but there is no academic consensus on an optimal plasmonic architecture for obtaining efficient phase control at high frequencies. This dissertation asks …


Reconstruction Of The 3d Temperature And Species Concentration Spatial Distribution Of A Jet Engine Exhaust Plume Using An Infrared Fourier Transform Spectrometer Hyperspectral Imager, Mason D. Paulec Sep 2018

Reconstruction Of The 3d Temperature And Species Concentration Spatial Distribution Of A Jet Engine Exhaust Plume Using An Infrared Fourier Transform Spectrometer Hyperspectral Imager, Mason D. Paulec

Theses and Dissertations

The measurement of combustion byproducts is useful for determining pollution of any fuel burning application, efficiency of combustion, and determining detectability of aircraft exhausts. Both intrusive and non-intrusive techniques have been utilized to measure these quantities. For the majority of the non-intrusive techniques, the absorption and emission spectra of the gases are utilized for measurements. For this research, the use of the Telops Infrared Fourier Transform Spectrometer (IFTS) Hyperspectral Imager (HSI) was explored within the scope of combustion diagnostic methods, as an option for remote measurements of a jet turbine to determine concentration of species and temperature of the combustion …


Application Of Spectral Solution And Neural Network Techniques In Plasma Modeling For Electric Propulsion, Joseph R. Whitman Sep 2018

Application Of Spectral Solution And Neural Network Techniques In Plasma Modeling For Electric Propulsion, Joseph R. Whitman

Theses and Dissertations

A solver for Poisson's equation was developed using the Radix-2 FFT method first invented by Carl Friedrich Gauss. Its performance was characterized using simulated data and identical boundary conditions to those found in a Hall Effect Thruster. The characterization showed errors below machine-zero with noise-free data, and above 20% noise-to-signal strength, the error increased linearly with the noise. This solver can be implemented into AFRL's plasma simulator, the Thermophysics Universal Research Framework (TURF) and used to quickly and accurately compute the electric field based on charge distributions. The validity of a machine learning approach and data-based complex system modeling approach …


Evaluation And Quantification Of Diffractive Plenoptic Camera Algorithm Performance, Jack A. Shepherd Iii Sep 2018

Evaluation And Quantification Of Diffractive Plenoptic Camera Algorithm Performance, Jack A. Shepherd Iii

Theses and Dissertations

A diffractive plenoptic camera is a novel approach to the traditional plenoptic camera which replaces the main optic with a Fresnel zone plate making the camera sensitive to wavelength instead of range. However, algorithms are necessary to reconstruct the image produced by plenoptic cameras. While many algorithms exist for traditional plenoptic cameras, their ability to create spectral images in a diffractive plenoptic camera is unknown. This paper evaluates digital refocusing, super resolution, and 3D deconvolution through a Richardson-Lucy algorithm as well as a new Gaussian smoothing algorithm. All of the algorithms worked well near the Fresnel zone plate design wavelength, …


Techniques For Improved Space Object Detection Performance From Ground-Based Telescope Systems Using Long And Short Exposure Images, David J. Becker Aug 2018

Techniques For Improved Space Object Detection Performance From Ground-Based Telescope Systems Using Long And Short Exposure Images, David J. Becker

Theses and Dissertations

Space object detection is of great importance in the highly dependent yet competitive and congested space domain. Detection algorithms employed play a crucial role in fulfilling the detection component in the space situational awareness mission to detect, track, characterize and catalog unknown space objects. Many current space detection algorithms use a matched filter or a spatial correlator on long exposure data to make a detection decision at a single pixel point of a spatial image based on the assumption that the data follows a Gaussian distribution. This research focuses on improving current space object detection algorithms and developing new algorithms …


Automating Mobile Device File Format Analysis, Richard A. Dill Aug 2018

Automating Mobile Device File Format Analysis, Richard A. Dill

Theses and Dissertations

Forensic tools assist examiners in extracting evidence from application files from mobile devices. If the file format for the file of interest is known, this process is straightforward, otherwise it requires the examiner to manually reverse engineer the data structures resident in the file. This research presents the Automated Data Structure Slayer (ADSS), which automates the process to reverse engineer unknown file for- mats of Android applications. After statically parsing and preparing an application, ADSS dynamically runs it, injecting hooks at selected methods to uncover the data structures used to store and process data before writing to media. The resultant …


Arrhenius Rate Chemistry-Informed Inter-Phase Source Terms (Arciist), Matthew J. Schwaab, Robert B. Greendyke, Bryan J. Steward Jul 2018

Arrhenius Rate Chemistry-Informed Inter-Phase Source Terms (Arciist), Matthew J. Schwaab, Robert B. Greendyke, Bryan J. Steward

Faculty Publications

Currently, in macro-scale hydrocodes designed to simulate explosive material undergoing shock-induced ignition, the state of the art is to use one of numerous reaction burn rate models. These burn models are designed to estimate the bulk chemical reaction rate. Unfortunately, these burn rate models are largely based on empirical data and must be recalibrated for every new material being simulated. We propose that the use of Arrhenius Rate Chemistry-Informed Interphase Source Terms (ARCIIST) in place of empirically derived burn models will improve the accuracy for these computational codes. A reacting chemistry model of this form was developed for the cyclic …


Efficient Phase Retrieval For Off-Axis Point Spread Functions, Salome Esteban Carrasco Jun 2018

Efficient Phase Retrieval For Off-Axis Point Spread Functions, Salome Esteban Carrasco

Theses and Dissertations

A novel pairing of phase retrieval tools allows for efficient estimation of pupil phase in optical systems from images of point spread functions (PSFs). The phase retrieval algorithm uses correlation of modeled phase in the focal plane to decouple aberrations that are difficult to identify in complex PSFs. The use of a phase kernel that departs from the Fresnel approximation for off-axis PSFs is a more accurate representation of wavefront phase in finite conjugate imaging. The combination of the approximation and phase correlation algorithm can be more efficient and accurate than generic algorithms.


Investigation Of Scramjet Flowfield Temperatures At The Boundary Layer With Hyperspectral Imaging, Amy M. Kerst Jun 2018

Investigation Of Scramjet Flowfield Temperatures At The Boundary Layer With Hyperspectral Imaging, Amy M. Kerst

Theses and Dissertations

Within the domain of chemical propulsion, the fields of combustion diagnostics and computational fluid dynamics each have a long history, and both have led to a better understanding of complex phenomena yielding practical improvements in propulsion systems. As more exotic forms of propulsion are developed, the importance of -- and often the challenges with -- both diagnostic and simulation capabilities also increase. In the case of scramjet combustion, these challenges primarily arise from the highly turbulent environment in the combustion cavity, and the high-speed, compressible nature of the flowfield. Efforts are underway to develop computer models of scramjet combustion environments …


Improved Space Object Detection Using Short-Exposure Image Data With Daylight Background, David J. Becker, Stephen C. Cain May 2018

Improved Space Object Detection Using Short-Exposure Image Data With Daylight Background, David J. Becker, Stephen C. Cain

Faculty Publications

No abstract provided.


Reference Dependence Of The Two-Determinant Coupled-Cluster Method For Triplet And Open-Shell Singlet States Of Biradical Molecules, Jesse J. Lutz, Marcel Nooijen, Ajith Perera, Rodney J. Bartlett Apr 2018

Reference Dependence Of The Two-Determinant Coupled-Cluster Method For Triplet And Open-Shell Singlet States Of Biradical Molecules, Jesse J. Lutz, Marcel Nooijen, Ajith Perera, Rodney J. Bartlett

Faculty Publications

We study the performance of the two-determinant (TD) coupled-cluster (CC) method which, unlike conventional ground-state single-reference (SR) CC methods, can, in principle, provide a naturally spin-adapted treatment of the lowest-lying open-shell singlet (OSS) and triplet electronic states. Various choices for the TD-CC reference orbitals are considered, including those generated by the multi-configurational self-consistent field method. Comparisons are made with the results of high-level SR-CC, equation-of-motion (EOM) CC, and multi-reference EOM calculations performed on a large test set of over 100 molecules with low-lying OSS states. It is shown that in cases where the EOMCC reference function is poorly described, TD-CC …


A Comparison Of High Frequency Angle Of Arrival And Ionosonde Data During A Traveling Ionospheric Disturbance, Kalen L. Knippling Mar 2018

A Comparison Of High Frequency Angle Of Arrival And Ionosonde Data During A Traveling Ionospheric Disturbance, Kalen L. Knippling

Theses and Dissertations

High Frequency (HF) geolocation techniques are commonly used to track the source of uncooperative HF emitters. A traveling ionospheric disturbance (TID) makes geolocation particularly difficult due to large perturbations in the local ionospheric electron density profile. Angle of Arrival (AoA) and ionosonde virtual height measurements collected at White Sands Missile Range, New Mexico in January 2014, are analyzed during a medium scale traveling ionospheric disturbance. TID characteristics are extracted from the measurements, and a comparison between the data sets is per- formed to provide a measure of correlation as a function of distance and time between the ionosonde and AoA …


Spatial Resolution And Contrast Of A Focused Diffractive Plenoptic Camera, Carlos D. Diaz Mar 2018

Spatial Resolution And Contrast Of A Focused Diffractive Plenoptic Camera, Carlos D. Diaz

Theses and Dissertations

The conventional Diffractive Plenoptic Camera (DPC) was developed as a system that would capture the spectral and spatial information of a scene in one snapshot. The conventional DPC couples a diffractive optic with plenoptic camera designs that provide snapshot spectral imaging capabilities but produce rendered images with low pixel count. A modified setup of the conventional DPC, the focused DPC, and a modified imaging algorithm, the refocused light field algorithm, were built and tested for the first time, and compared to the conventional DPC as methods that would increase the pixel count and improve rendered image quality. The focused DPC …


Modeling A Space-Based Quantum Link, Alexander W. Duchane Mar 2018

Modeling A Space-Based Quantum Link, Alexander W. Duchane

Theses and Dissertations

Quantum sources and single photon detectors have improved, allowing quantum algorithms for communication, encryption, computing, and sensing to transition from theory and small-scale laboratory experiments to field experiments. One such quantum algorithm, Quantum Key Distribution, uses optical pulses to generate shared random bit strings between two locations. These shared bit strings can be turned into encryption keys to be used as a one-time-pad or integrated with symmetric encryption techniques such as the Advanced Encryption Standard. This method of key generation and encryption is resistant to future advances in quantum computing which significantly degrade the effectiveness of current asymmetric key sharing …


Pulse Height Spectra Analysis Of A Neutron Energy Tuning Assembly, Jason R. Stickney Mar 2018

Pulse Height Spectra Analysis Of A Neutron Energy Tuning Assembly, Jason R. Stickney

Theses and Dissertations

An energy tuning assembly (ETA) was previously designed and built for the purpose of irradiating samples with a combination of a thermonuclear and a prompt fission neutron spectrum. Initial research was performed to characterize the performance of the ETA at the Lawrence Berkeley National Laboratory 88-Inch Cyclotron using 33 MeV deuteron breakup on tantalum as the neutron source. This research analyzes detector responses collected from three EJ-309 detectors used to characterize the ETA generated neutron field. A signal processing chain was developed to reduce the full waveform data into a pulse height spectrum. The primary goal was to develop a …


Wall-Modeled Large Eddy Simulation Of A Three-Dimensional Shock-Boundary Layer Interaction, Nicholas J. Marco Mar 2018

Wall-Modeled Large Eddy Simulation Of A Three-Dimensional Shock-Boundary Layer Interaction, Nicholas J. Marco

Theses and Dissertations

The direct simulation of turbulent flows is prohibitive at high Reynolds numbers; thus, methods such as RANS and LES are used. However, these methods still require a large number of cells near a solid boundary. To circumvent this issue, a Wall-Modeled Large Eddy Simulation (WM-LES) can be used. Of interest is how these wall models perform in comparison to a Wall-Resolved Large Eddy Simulation (WR-LES) and experimental results of a shock turbulent boundary layer interactions (STBLI) and specifically, whether equilibrium wall models are sufficient to resolve the oscillatory and hence non-equilibrium nature of these flows or whether a non-equilibrium model …


Characterization Of The Effects Of Heavy Charged Particle Exposure On The Radiation Resistant Bacterium Deinococcus Radiodurans, Todd A. Bryant Mar 2018

Characterization Of The Effects Of Heavy Charged Particle Exposure On The Radiation Resistant Bacterium Deinococcus Radiodurans, Todd A. Bryant

Theses and Dissertations

Although not an extremophile, Deinococcus radiodurans has proven to have exceptional resistance to ionizing radiation, specifically via gamma and X-ray photons. To date, no known experiments have bombarded the bacterium with charged particles larger than hydrogen. This study explored the effects on the organism’s ability to survive high linear energy transfer heavy-charged particle exposures of oxygen ions. It also investigated the effects of low linear energy transfer ultraviolet radiation on various mutants. Two uvrB mutants were created to ascertain the importance of the gene in single-strand break repair following gamma irradiation and two recF mutants were created to explore the …


Characterization Of Silicon Ion Exposure On Deinococcus Radiodurans, Richard F. Daughtry Mar 2018

Characterization Of Silicon Ion Exposure On Deinococcus Radiodurans, Richard F. Daughtry

Theses and Dissertations

Deinococcus radiodurans is a robust bacterium that is known for its extraordinary resistance to ionizing radiation. In general, many of the investigations of this bacterium's resistance have revolved around low linear energy transfer radiation, such as gamma and electron radiation. This study explored Deinococcus radiodurans's ability to survive high linear energy transfer radiation, specifically proton and neutron radiation. Deinococcus radiodurans was dehydrated to reduce the effects of low linear energy transfer radiation. The bacteria were exposed to both neutron and proton radiation of varying amounts and rehydrated. The resulting colonies were counted and compared to colonies of non-irradiated control samples …


Two-Photon Excitation Of Cesium Alkali Metal Vapor 72D, 82D Kinetics And Spectroscopy, Ricardo C. Davila Mar 2018

Two-Photon Excitation Of Cesium Alkali Metal Vapor 72D, 82D Kinetics And Spectroscopy, Ricardo C. Davila

Theses and Dissertations

Pulsed excitation on the two-photon Cs 62S½ → 72D3/2,5/2 transition results in time-resolved fluorescence at 697 nm and 672 nm. The rates for fine structure mixing between the 72D3/2,5/2 states have been measured for helium and argon rare gas collision partners. The mixing rates are very fast, 1.26 ± 0.05 x 10-9 cm3/(atom sec) for He and 1.52 ± 0.05 x 10-10 cm3 /(atom sec) for Ar, driven by the small energy splitting and large radial distribution for the valence electron. …


Impacts Of Sub-Auroral Polarization Streams On High Frequency Operations As A Function Of Modeled Particle Energy Flux, Nathan D. Smith Mar 2018

Impacts Of Sub-Auroral Polarization Streams On High Frequency Operations As A Function Of Modeled Particle Energy Flux, Nathan D. Smith

Theses and Dissertations

Space weather events can cause irregularities within the ionosphere; in particular, this research examines sub-auroral polarization streams (SAPS), as their accompanying irregularities and effects can degrade high-frequency (HF) signal propagation. It is known that the strongest westerly current drifts delineating SAPS are associated with a deep ionospheric trough, which in turn contaminates HF data with clutter from the non-standard ionosphere. Having a methodology to track and identify these occurrences on current computational architecture would provide operators enhanced situational awareness in knowing to expect degradation in HF processes. This study has discovered a weak, yet significant, exponentially decaying correlation between maximum …


Improving Fallout Characterization By Using Multivariate Techniques To Determine Composition, Christopher R. Pitkins Mar 2018

Improving Fallout Characterization By Using Multivariate Techniques To Determine Composition, Christopher R. Pitkins

Theses and Dissertations

Multivariate statistical techniques have been applied in order to un-mix nuclear fallout debris chemical data. This information is critical to characterization of fallout particle formation following a nuclear detonation. Understanding the correlation between environmental precursors and actinide concentrations in post-detonation nuclear fallout material aids in understanding the physical and chemical processes that alter nuclear device signatures in the fireball. This research examines 123 nuclear fallout samples from a historical nuclear test. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) are used to collect chemical compositions of the fallout samples. Principal component analysis (PCA) is applied in order to examine …


Plasmonic Grating Geometrics And Wavelength-Dependent Focus Depth In Infrared Detectors, Patrick R. Kennedy Mar 2018

Plasmonic Grating Geometrics And Wavelength-Dependent Focus Depth In Infrared Detectors, Patrick R. Kennedy

Theses and Dissertations

The objective for this research is to determine a relationship between plasmonic grating geometries and the wavelength-dependent focus depth. This research is focused on enhancing the signal collected by infrared detectors by using a metal grating as a planar lens to focus light in the detecting region of the substrate. This can be used to maintain a thinner absorbing region and possibly to create multi-color imaging in a single pixel. Simulations demonstrate that the plasmonic lens is capable of creating a wavelength dependent focus spot.


Using An Astrophysical Model To Characterize Nuclear Dust, Anita N. Dunsmore Mar 2018

Using An Astrophysical Model To Characterize Nuclear Dust, Anita N. Dunsmore

Theses and Dissertations

Dust clouds resulting from nuclear explosions are complex phenomena, and knowledge on how they form is lacking. Noting the similarities between supernovae and nuclear explosions led to the concept of modeling a nuclear dust cloud using a supernova simulation. MOCASSIN uses a Monte Carlo approach to model photons traveling through a dust cloud, allowing the cloud's characteristics to be discovered by comparing an observed spectrum to a calculated one and then changing input values to make the spectra match. Data files describing two nuclear fireballs of varying yields were created and analyzed using MOCASSIN, but yielded zero energy spectra. After …


Comparison Of Plume Dynamics For Laser Ablated Metals: Al And Ti, William A. Bauer, Glen P. Perram, Timothy Haugan Mar 2018

Comparison Of Plume Dynamics For Laser Ablated Metals: Al And Ti, William A. Bauer, Glen P. Perram, Timothy Haugan

Faculty Publications

Emissive plumes from pulsed laser ablation of bulk Ti and Al from KrF laser irradiation at laser fluence up to 3.5 J/cm2 and argon background pressures of 0–1 Torr have been observed using gated intensified charged-coupled device imagery. Mass loss for Ti increases from 0.1 to 0.8 μg/pulse as pulse energy increase from 174 to 282 mJ/pulse (35–170 photons/atom) and decreases by ∼30% as pressure increases from vacuum to 1 Torr. Early plume energies are described by the free expansion velocities of 1.57 ± 0.02 and of 1.81 ± 0.07 cm/μs for Ti and Al, respectively, …


Demonstration Of Versatile Whispering-Gallery Micro-Lasers For Remote Refractive Index Sensing, Lei Wan, Hengky Chandrahalim, Jian Zhou Mar 2018

Demonstration Of Versatile Whispering-Gallery Micro-Lasers For Remote Refractive Index Sensing, Lei Wan, Hengky Chandrahalim, Jian Zhou

Faculty Publications

We developed chip-scale remote refractive index sensors based on Rhodamine 6G (R6G)-doped polymer micro-ring lasers. The chemical, temperature, and mechanical sturdiness of the fused-silica host guaranteed a flexible deployment of dye-doped polymers for refractive index sensing. The introduction of the dye as gain medium demonstrated the feasibility of remote sensing based on the free-space optics measurement setup. Compared to the R6G-doped TZ-001, the lasing behavior of R6G-doped SU-8 polymer micro-ring laser under an aqueous environment had a narrower spectrum linewidth, producing the minimum detectable refractive index change of 4 x 10−4 RIU. The maximum bulk refractive index sensitivity (BRIS) …


Influence Of Basis-Set Size On The X2Σ+1/2, A2Π1/2, A2Π3/2, And B2Σ1/2 Potential-Energy Curves, A2Π3/2 2 Vibrational Energies, And D1 And D2 Line Shapes Of Rb+He, L. Aaron Blank, Amit R. Sharma, David E. Weeks Mar 2018

Influence Of Basis-Set Size On The X2Σ+1/2, A2Π1/2, A2Π3/2, And B2Σ1/2 Potential-Energy Curves, A2Π3/2 2 Vibrational Energies, And D1 And D2 Line Shapes Of Rb+He, L. Aaron Blank, Amit R. Sharma, David E. Weeks

Faculty Publications

The X 2 Σ + 1 / 2 , A 2 Π 1 / 2 , A 2 Π 3 / 2 , and B 2 Σ + 1 / 2 potential-energy curves for Rb+He are computed at the spin-orbit multireference configuration interaction level of theory using a hierarchy of Gaussian basis sets at the double-zeta (DZ), triple-zeta (TZ), and quadruple-zeta (QZ) levels of valence quality. Counterpoise and Davidson-Silver corrections are employed to remove basis-set superposition error and ameliorate size-consistency error. An extrapolation is performed to obtain a final set of potential-energy curves in the complete basis-set (CBS) limit. This …