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Full-Text Articles in Physics

Using Time-Resolved Photoluminescence To Measure The Excitation And Temperature Dependence Of Carrier Relaxation In Mid-Wave Infrared Semiconductors, Kevin Cumblidge Jun 2004

Using Time-Resolved Photoluminescence To Measure The Excitation And Temperature Dependence Of Carrier Relaxation In Mid-Wave Infrared Semiconductors, Kevin Cumblidge

Theses and Dissertations

Research in the field of mid-wave infrared (MWIR) semiconductor photonic devices has led to applications in a variety of disciplines including atmospheric monitoring, optical communications, non-invasive glucose testing for diabetics, and infrared (IR) countermeasures. One of the limiting factors for improving the modulation rates of MWIR devices is the carrier relaxation time. This is the time required for energetic carriers to cool to the edge of their respective bands in a bulk semiconductor material, or to the bottom of a well through inter- and intra-sub-band scattering in a quantum well (QW) structure. From these lower energy states, they can then …


Analysis Of Uncertainties In Infrared Camera Measurements Of A Turbofan Engine In An Altitude Test Cell, Thomas A. Morris Mar 2004

Analysis Of Uncertainties In Infrared Camera Measurements Of A Turbofan Engine In An Altitude Test Cell, Thomas A. Morris

Theses and Dissertations

This research investigated the uncertainties in measuring the IR signature of a General Electric F110-GE-129 turbofan engine inside an altitude test cell. The requirements for the measurement system include the intensity and radiance of the engine surfaces in three bands of operation, two Medium Wave IR (MWIR) bands and one Long Wave IR (LWIR) band. The altitude test cell provides a venue for measuring the IR signature in simulated altitude operation, but the imaging process is laden with measurement uncertainty due to stray radiation from the facility structure, hot exhaust gases, and the measurement equipment itself. The atmosphere and a …


Spectral And Temporal Characterization Of High Temperature Events, William F. Bagby Mar 2001

Spectral And Temporal Characterization Of High Temperature Events, William F. Bagby

Theses and Dissertations

The remote observations of the temporal and spectral characteristics of the infrared (IR) emissions from exploding ordnance have been correlated with explosion conditions. A Bomem MR-154 Fourier Transform Interferometer with two detectors, InSb and HgCdTe, was used to record spectra in the 1.3 - 20 micrometers range. Data was collected at spectral resolutions of 16/cm and 4/cm, and temporal resolutions of 0.045 sand 0.123 5, respectively. The data files range in size from 900 Kilobytes to several Megabytes. These are reduced to 2-dimensional representations of temporal features that are less than 100 Kilobytes. The data analysis indicates the possibility of …


Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager Dec 1995

Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager

Theses and Dissertations

Slow desorption of contaminants from soil presents one of the greatest challenges to modeling contaminant fate and transport and implementing effective remediation technologies. The kinetics of long-term desorption of trichloroethylene (TCE) from powdered clay soils were studied to determine the desorption rates and mechanism. Infrared absorption spectroscopy was used to monitor the concentration of TCE desorbed from contaminated flint clay for 71 hours. Observed gas phase TCE concentrations as a function of time were compared to that predicted by a one-site Langmuir desorption mechanism. The Langmuir model, with a single type of bonding site, did not account for the release …


Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt Sep 1994

Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt

Theses and Dissertations

This research investigated the influence of soil characteristics on the desorption of trichloroethylene (TCE). TCE is one of the most common contaminants at Superfund sites. Unfortunately, extraction of TCE from contaminated soils has been hindered by its slow and poorly understood desorption from soil particles. The rate and progress of desorption of TCE from seven types of soil with varying particle diameters and elemental compositions was measured using optical absorption techniques. Fitting the data to the Langmuir Isotherm functional form predicted in the literature yielded parameters for the desorption rate and total amount desorption each soil type. These parameters were …


Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares Aug 1994

Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares

Theses and Dissertations

This thesis investigated the influence of temperature on the desorption rated of trichloroethylene (TCE) from plastic clay. It was expected that an increase in temperature will cause an increase in both the desorption rates of TCE and in the desorbed quantity. Previous studies on other chemicals indicated a faster decrease in the remaining sorbed concentration with an increase in temperature. This research made use of the infrared optical absorption technique. IR spectroscopy was used to measure the concentration of the vapor TCE that desorbed from the soil. The soil was exposed to liquid TCE for 2 days then placed inside …