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Articles 1 - 25 of 25
Full-Text Articles in Physics
Ultrasound-Assisted Air-Jet Spinning Of Silk Fibroin-Soy Protein Nanofiber Composite Biomaterials., Futian Yang, Fang Wang, Janine Mazahreh, Xiao Hu
Ultrasound-Assisted Air-Jet Spinning Of Silk Fibroin-Soy Protein Nanofiber Composite Biomaterials., Futian Yang, Fang Wang, Janine Mazahreh, Xiao Hu
Faculty Scholarship for the College of Science & Mathematics
Ultrasound utilizes a non-radiation technology that can meet modern standards to gain access to cheap, reliable and sustainable modern energy. Ultrasound technology can be implemented in the field of biomaterials for its exceptional potential in controlling the shape of nanomaterials. This study presents the first example of the production of soy and silk fibroin protein composite nanofibers in various ratios via combining ultrasonic technology with air-spray spinning. Characterization of ultrasonic spun nanofibers was performed by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric (TG) analysis, water contact angle, water retention, enzymatic …
Coil-To-Bridge Transitions Of Self-Assembled Water Chains Observed In A Nanoscopic Meniscus, Byung I. Kim, Ryan D. Boehm, Harrison Agrusa
Coil-To-Bridge Transitions Of Self-Assembled Water Chains Observed In A Nanoscopic Meniscus, Byung I. Kim, Ryan D. Boehm, Harrison Agrusa
Physics Faculty Publications and Presentations
Ten downward portions in the large oscillatory force–distance curve reported earlier are analyzed to understand a nanoscale water meniscus confined between a sharp probe and a flat substrate in air. The sigmoidal shape of each portion leads to the assumption that the meniscus is made up of n independent transitions of two states: one for a coil state and the other for a bridge state. The analysis reveals that each downward portion occurs due to a coil-to-bridge transition of n self-assembled water chains whose length ranges between 197 and 383 chain units. The transition provides novel insights into water’s unique …
Ultrasound Regulated Flexible Protein Materials: Fabrication, Structure And Physical-Biological Properties., Bowen Cai, Hanling Gu, Fang Wang, Kyle Printon, Zhenggui Gu, Xiao Hu
Ultrasound Regulated Flexible Protein Materials: Fabrication, Structure And Physical-Biological Properties., Bowen Cai, Hanling Gu, Fang Wang, Kyle Printon, Zhenggui Gu, Xiao Hu
Faculty Scholarship for the College of Science & Mathematics
Ultrasound can be used in the biomaterial field due to its high efficiency, easy operation, no chemical treatment, repeatability and high level of control. In this work, we demonstrated that ultrasound is able to quickly regulate protein structure at the solution assembly stage to obtain the designed properties of protein-based materials. Silk fibroin proteins dissolved in a formic acid-CaCl solution system were treated in an ultrasound with varying times and powers. By altering these variables, the silks physical properties and structures can be fine-tuned and the results were investigated with Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron …
Protein Conformational Entropy Is Not Slaved To Water, Bryan S Marques, Matthew A Stetz, Christine Jorge, Kathleen G Valentine, A Joshua Wand, Nathaniel V Nucci
Protein Conformational Entropy Is Not Slaved To Water, Bryan S Marques, Matthew A Stetz, Christine Jorge, Kathleen G Valentine, A Joshua Wand, Nathaniel V Nucci
Faculty Scholarship for the College of Science & Mathematics
Conformational entropy can be an important element of the thermodynamics of protein functions such as the binding of ligands. The observed role for conformational entropy in modulating molecular recognition by proteins is in opposition to an often-invoked theory for the interaction of protein molecules with solvent water. The "solvent slaving" model predicts that protein motion is strongly coupled to various aspects of water such as bulk solvent viscosity and local hydration shell dynamics. Changes in conformational entropy are manifested in alterations of fast internal side chain motion that is detectable by NMR relaxation. We show here that the fast-internal side …
Impact Of Bubble Baths On Stainless Steel Sphere Water Entry, Wesley Robinson
Impact Of Bubble Baths On Stainless Steel Sphere Water Entry, Wesley Robinson
Physics Capstone Projects
Soap Bubbles on the water surface would seem to be an intuitive means for splash suppression, but their presence appears to be a double edged sword. We present on the water entry of hydrophilic spheres where the liquid surface is augmented by the presence of a bubble layer, similar to a bubble bath. While the presence of a bubble layer can diminish splashing upon impact at low Weber numbers, it also induces cavity formation at speeds below the critical velocity. The formation of a cavity generally results in larger Worthington jets and thus, larger amounts of ejected liquid. Bubble layers …
Fluted Films, Nathan B. Spiers, Mohammad M. Mansoor, Jesse Belden, Randy Craig Hurd, Zhao Pan, Tadd T. Truscott
Fluted Films, Nathan B. Spiers, Mohammad M. Mansoor, Jesse Belden, Randy Craig Hurd, Zhao Pan, Tadd T. Truscott
Mechanical and Aerospace Engineering Faculty Publications
This paper is associated with a poster winner of a 2017 APS/DFD Milton van Dyke Award for work presented at the DFD Gallery of Fluid Motion. The original poster is available from the Gallery of Fluid Motion, https://doi.org/10.1103/APS.DFD.2017.GFM.P0030
Enhanced Acidity Of Acetic And Pyruvic Acids On The Surface Of Water, Alexis J. Eugene, Elizabeth A. Pillar, Agustín J. Colussi, Marcelo I. Guzman
Enhanced Acidity Of Acetic And Pyruvic Acids On The Surface Of Water, Alexis J. Eugene, Elizabeth A. Pillar, Agustín J. Colussi, Marcelo I. Guzman
Chemistry Faculty Publications
Understanding the acid–base behavior of carboxylic acids on aqueous interfaces is a fundamental issue in nature. Surface processes involving carboxylic acids such as acetic and pyruvic acids play roles in (1) the transport of nutrients through cell membranes, (2) the cycling of metabolites relevant to the origin of life, and (3) the photooxidative processing of biogenic and anthropogenic emissions in aerosols and atmospheric waters. Here, we report that 50% of gaseous acetic acid and pyruvic acid molecules transfer a proton to the surface of water at pH 2.8 and 1.8 units lower than their respective acidity constants pKa …
Analysis Of The Red And Green Optical Absorption Spectrum Of Gas Phase Ammonia, Nikolai F. Zobov, Phillip A. Coles, Roman I. Ovsyannikov, Aleksandra A. Kyuberis, Robert J. Hargreaves, Peter F. Bernath, Jonathan Tennyson, Sergei N. Yurchenko, Oleg L. Polyansky
Analysis Of The Red And Green Optical Absorption Spectrum Of Gas Phase Ammonia, Nikolai F. Zobov, Phillip A. Coles, Roman I. Ovsyannikov, Aleksandra A. Kyuberis, Robert J. Hargreaves, Peter F. Bernath, Jonathan Tennyson, Sergei N. Yurchenko, Oleg L. Polyansky
Chemistry & Biochemistry Faculty Publications
Room temperature NH3 absorption spectra recorded at the Kitt Peak National Solar Observatory in 1980 are analyzed. The spectra cover two regions in the visible: 15,200 - 15,700 cm-1 and 17,950 - 18,250 cm-1. These high overtone rotation-vibration spectra are analyzed using both combination differences and variational line lists. Two variational line lists were computed using the TROVE nuclear motion program: one is based on an ab initio potential energy surface (PES) while the other used a semi-empirical PES. Ab initio dipole moment surfaces are used in both cases. 95 energy levels with J = 1 …
Mineral Physics Modeling Of The Effect Of Water On Crustal Seismic Velocity Ratios, Eric Lyman
Mineral Physics Modeling Of The Effect Of Water On Crustal Seismic Velocity Ratios, Eric Lyman
Physics Capstone Projects
This research explores the relationship between the presence of water (H2O) in the make up of rocks and minerals (specifically quartz) at different levels in the crust. The relationships were calculated using Perple_x software to adjust the level of the different chemical and mineral make up of the rock. The densities were calculated using the velocity of primary waves and shear waves as collected by Tony Lowry. There seems to be at least a casual link between water content and quartz content.
Experiments On Tracer Diffusion In Aqueous And Non-Aqueous Solvent Combinations, Duncan M. Frasch, Daniel Spiegel
Experiments On Tracer Diffusion In Aqueous And Non-Aqueous Solvent Combinations, Duncan M. Frasch, Daniel Spiegel
Physics and Astronomy Faculty Research
Forced Rayleigh scattering is used to study the tracer diffusion of an azobenzene in binary combinations of polar solvents, including water. In the absence of water, the tracer diffusion coefficient D in the mixture lies between the diffusion coefficients within the pure solvents, on a curve that is reasonably close to the prediction of free-volume theory. If water is present, on the other hand, the diffusion coefficient displays a minimum that is less than the smaller of the two pure-solvent values. We attempt to understand the different behavior in water by concentrating on the fairly hydrophobic nature of the solute, …
Direct Observation Of Self-Assembled Chain-Like Water Structures In A Nanoscopic Water Meniscus, Byung I. Kim, Ryan D. Boehm, Jeremy R. Bonander
Direct Observation Of Self-Assembled Chain-Like Water Structures In A Nanoscopic Water Meniscus, Byung I. Kim, Ryan D. Boehm, Jeremy R. Bonander
Physics Faculty Publications and Presentations
Sawtooth-like oscillatory forces generated by water molecules confined between two oxidized silicon surfaces were observed using a cantilever-based optical interfacial force microscope when the two surfaces approached each other in ambient environments. The humidity-dependent oscillatory amplitude and periodicity were 3-12 nN and 3-4 water diameters, respectively. Half of each period was matched with a freely jointed chain model, possibly suggesting that the confined water behaved like a bundle of water chains. The analysis also indicated that water molecules self-assembled to form chain-like structures in a nanoscopic meniscus between two hydrophilic surfaces in air. From the friction force data measured simultaneously, …
Musical Acoustics Of Orchestral Water Crotales, Rand Worland
Musical Acoustics Of Orchestral Water Crotales, Rand Worland
All Faculty Scholarship
An experimental investigation of orchestral crotale vibrational modes in water is presented, along with a qualitative virtual mass model describing the observed effects. Changes in frequency, overtone ratio, and mode splitting as a function of water depth are reported for a C6 crotale using electronic speckle-pattern interferometry. These data are related to perceived changes in pitch and timbre, along with the creation of audible beats at particular water depths. It is also shown that the suspension method used by musicians when dipping crotales into water leads to the creation of additional acoustically significant modes that are not excited when …
The Design And Construction Of A Microgravity Boiling Experiment, Troy Munro
The Design And Construction Of A Microgravity Boiling Experiment, Troy Munro
Presentations
No abstract provided.
What Is Wrong With Water Barometers?, Dan Sullivan, Robert W. Smith, E. J. Kemnitz, Kevin Barton, Robert M. Graham, Raymond A. Guenther, Larry Webber
What Is Wrong With Water Barometers?, Dan Sullivan, Robert W. Smith, E. J. Kemnitz, Kevin Barton, Robert M. Graham, Raymond A. Guenther, Larry Webber
Chemistry Faculty Publications
Every student who studies atmospheric pressure in physics or chemistry learns the principles behind the construction of barometers. Cistern barometers, such as those found in most laboratories, consist of a long glass tube containing an inverted column of liquid having an open end in a cistern of the liquid. Students learn that the column of liquid is supported by air pressure and is equal in weight to a column of air of the same diameter.
Charge Exchange And X-Ray Emission Cross Sections For Multiply Charged Ions Colliding With H₂O, Sebastian Otranto, Ronald E. Olson
Charge Exchange And X-Ray Emission Cross Sections For Multiply Charged Ions Colliding With H₂O, Sebastian Otranto, Ronald E. Olson
Physics Faculty Research & Creative Works
Total and state selective nl-electron capture cross sections are presented for highly charged ions Z=4-10, 14, 18, and 26 colliding with water molecules. The energy range investigated was from 10 eV/amu (v=0.02 a.u.) to 100 keV/amu (v=2 a.u.). An initialization for the 1B1 and 3A1 orbitals of the water molecule is introduced based on the one center expansion of Moccia and compared to our previous studies based on a hydrogenic approximation within the microcanonical ensemble. The Z dependence of the calculated total cross sections is in reasonable agreement with the recent data of Mawhorter et al. [Phys. Rev. A 75, …
Development Of A Novel Modular Mid-Infrared Sensor For The In-Situ Detection Of The Btex Compounds In Water, Raymond Mccue
Development Of A Novel Modular Mid-Infrared Sensor For The In-Situ Detection Of The Btex Compounds In Water, Raymond Mccue
Doctoral
This research thesis describes the design, construction and testing of a novel modular mid-infrared fibre optic sensing system for the detection of hydrocarbons in water. It is the adverse effects to these hydrocarbon pollutants on flora and fauna that has led to the development of sensing systems for their detection and quantification. The key sensor design feature, its modularity, utilises simple low cost commercially available optical components, which are inherently suited to construct compact rugged sensing systems to perform in-situ measurements which are ideally preferred for environmental sensing. The various laboratory-based prototypes constructed weee calibrated for two target analytes over …
Screened-Exchange Determination Of The Electronic Properties Of Monoclinic, Tetragonal And Cubic Zirconia, Julia E. Medvedeva, C. B. Geller, D. M. Rishel, Arthur J. Freeman
Screened-Exchange Determination Of The Electronic Properties Of Monoclinic, Tetragonal And Cubic Zirconia, Julia E. Medvedeva, C. B. Geller, D. M. Rishel, Arthur J. Freeman
Physics Faculty Research & Creative Works
First-principles electronic band structure investigations of monoclinic, tetragonal, and cubic ZrO2 reveal the highly anisotropic nature of the conduction and valence band topologies in the monoclinic phase with electron and hole effective masses differing by over an order of magnitude in perpendicular directions. The planes of relatively high implied electron and hole mobilities intersect along a single crystallographic direction, making this the only direction readily available for exciton motion. Conversely, in the tetragonal and cubic phases, charge carrier effective masses are more isotropic and exciton motion is less restricted. These findings may explain recent experimental observations suggesting that exciton production …
Temperature Dependence Of Homogeneous Nucleation Rates For Water: Near Equivalence Of The Empirical Fit Of Wölk And Strey, And The Scaled Nucleation Model, Barbara N. Hale
Physics Faculty Research & Creative Works
It is pointed out that the temperature fitting function of Wölk and Strey [J. Phys. Chem. 105, 11683 (2001)], recently shown to convert the Becker-Döring [Ann. Phys. (Leipzig) 24, 719 (1935)] nucleation rate into an expression in agreement with much of the experimental water nucleation rate data, also converts the Becker-Döring rate into a form nearly equivalent with the scaled nucleation rate model, Jscaled=Joc exp[-16πΩ3(Tc/T-1)3/3(ln S)2]. In the latter expression Joc is the inverse thermal wavelength cubed/sec, evaluated at Tc.
Nucleation Rates Of Water And Heavy Water Using Equations Of State, Abdalla Obeidat, Jin-Song Li, Gerald Wilemski
Nucleation Rates Of Water And Heavy Water Using Equations Of State, Abdalla Obeidat, Jin-Song Li, Gerald Wilemski
Physics Faculty Research & Creative Works
The original formula of Gibbs for the reversible work of critical nucleus formation is evaluated in three approximate ways for ordinary and heavy water. The least approximate way employs an equation of state to evaluate the pressure difference between the new and old phases. This form of the theory yields a temperature dependence for the nucleation rate close to that observed experimentally. This is a substantial improvement over the most commonly used (and most approximate) form of classical theory.©2004 American Institute of Physics.
Photofragmentation Dynamics Of Core-Excited Water By Anion-Yield Spectroscopy, Wayne C. Stolte, M. M. Sant'anna, Gunnar Ohrwall, Maria Novella Piancastelli, I. Dominguez-Lopez, Dennis W. Lindle
Photofragmentation Dynamics Of Core-Excited Water By Anion-Yield Spectroscopy, Wayne C. Stolte, M. M. Sant'anna, Gunnar Ohrwall, Maria Novella Piancastelli, I. Dominguez-Lopez, Dennis W. Lindle
Chemistry and Biochemistry Faculty Research
Partial-anion and- cation yields from H2O are presented for photon energies near the oxygen K edge. The O- yield exhibits a feature above threshold attributed to doubly excited states, in contrast to the H- and cation yields, which are nearly featureless above threshold. Additionally, the lack of the OH- fragment indicates radiative decay and provides a negligible amount of anion formation.
Mim And Nonlinear Least-Squares Inversions Of Aem Data In Barataria Basin, Louisiana, Melissa Whitten Bryan, Kenneth W. Holladay, Clyde J. Bergeron Jr., Juliette W. Ioup, George E. Ioup
Mim And Nonlinear Least-Squares Inversions Of Aem Data In Barataria Basin, Louisiana, Melissa Whitten Bryan, Kenneth W. Holladay, Clyde J. Bergeron Jr., Juliette W. Ioup, George E. Ioup
Physics Faculty Publications
An airborne electromagnetic survey was performed over the marsh and estuarine waters of the Barataria basin of Louisiana. Two inversion methods were applied to the measured data to calculate layer thicknesses and conductivities: the modified image method (MIM) and a nonlinear least-squares method of inversion using two two-layer forward models and one three-layer forward model, with results generally in good agreement. Uniform horizontal water layers in the near-shore Gulf of Mexico with the fresher (less saline, less conductive) water above the saltier (more saline, more conductive) water can be seen clearly. More complex near-surface layering showing decreasing salinity/conductivity with depth …
An Ab Initio Study Of Specific Solvent Effects On The Electronic Coupling Element In Electron Transfer Reactions, Thomas M. Henderson '98, Robert J. Cave
An Ab Initio Study Of Specific Solvent Effects On The Electronic Coupling Element In Electron Transfer Reactions, Thomas M. Henderson '98, Robert J. Cave
All HMC Faculty Publications and Research
Specific solvent effects on the electronic coupling element for electron transfer are examined using two model donor–acceptor systems (Zn2+ and Li2+) and several model “solvent” species (He, Ne, H2O, and NH3). The effects are evaluated relative to the given donor–acceptor pair without solvent present. The electronic coupling element (Hab) is found to depend strongly on the identity of the intervening solvent, with He atoms decreasing Hab, whereas H2O and NH3 significantly increase Hab. The distance dependence (essentially exponential decay) is weakly affected by a single intervening solvent atom–molecule. However, when the donor–acceptor distance increases in concert with addition of successively …
The Evolution Of Density-Driven Circulation Over Sloping Bottom Topography, G. H. Wheless, J. M. Klinck
The Evolution Of Density-Driven Circulation Over Sloping Bottom Topography, G. H. Wheless, J. M. Klinck
CCPO Publications
The short timescale temporal evolution of buoyancy-driven coastal flow over sloping bottom topography is examined using a two-dimensional, vertically averaged numerical model. Winter shelf circulation driven by a coastal ''point source'' buoyancy flux is modeled by initiating a coastal outflow with density anomaly epsilon into well-mixed shelf water. The nonlinear interaction between the time-varying velocity and density field is represented by an advection-diffusion equation. Three cases are discussed: that of a buoyant (epsilon < 0) outflow, a neutral (epsilon = 0) outflow, and a dense (epsilon > 0) outflow. Results are similar to observations from well-mixed shelf areas and show that density-topography interactions are capable of substantially influencing coastal circulation. A negative (buoyant) coastal …
Condensation Coefficient Measurement For Water In The Umr Cloud Simulation Chamber, Donald E. Hagen, John L. Schmitt, Max B. Trueblood, John C. Carstens, Daniel R. White, Darryl J. Alofs
Condensation Coefficient Measurement For Water In The Umr Cloud Simulation Chamber, Donald E. Hagen, John L. Schmitt, Max B. Trueblood, John C. Carstens, Daniel R. White, Darryl J. Alofs
Physics Faculty Research & Creative Works
A systematic series of condensation coefficient measurements of water have been made using the University of Missouri-Rolla cooled-wall expansion chamber which simulates the thermodynamics of cloud. This coefficient is seen to decrease from a value near unity, at the outset of simulation, to a value in the neighborhood of 0.01 toward the end of a simulation. Final values of this coefficient are sufficiently low as to contribute significantly to the broadening of the drop-size distribution in cloud.
Temperature And Supersaturation Dependent Nucleation Rates Of Water By Molecular Cluster Model Calculations, Sung-Ho Suck Salk, Chen K. Lutrus, Donald E. Hagen
Temperature And Supersaturation Dependent Nucleation Rates Of Water By Molecular Cluster Model Calculations, Sung-Ho Suck Salk, Chen K. Lutrus, Donald E. Hagen
Physics Faculty Research & Creative Works
Using a microphysical approach to nucleation, we present an extensive study of water nucleation rates for wide ranges of both temperature and supersaturation ratio. Based on the fundamental molecular properties of clusters instead of bulk properties, the microphysical approach is demonstrated to predict good agreement with measured nucleation rates over this broad range of conditions. Predicted critical sizes for nucleation are found to be relatively small, and are in the molecular cluster size regime rather than in a size regime that should be characterized by bulk values. Estimated sticking coefficient values cover the range of ~0.9 to ~0.2 for the …