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Full-Text Articles in Physics

3d Transition Metal Doping Of Semiconducting Boron Carbides, Peter A. Dowben, Orhan Kizilkaya, Jing Liu, B. Montag, K. Nelson, Ildar F. Sabiryanov, Jennifer I. Brand Jan 2009

3d Transition Metal Doping Of Semiconducting Boron Carbides, Peter A. Dowben, Orhan Kizilkaya, Jing Liu, B. Montag, K. Nelson, Ildar F. Sabiryanov, Jennifer I. Brand

Peter Dowben Publications

The introduction metallocenes, in particular ferrocene (Fe(η5-C5H5)2), cobaltocene (Co(η5-C5H5)2), and nickelocene (Ni(η5-C5H5)2), together with the carborane source molecule closo-1,2-dicarbadodecaborane, during plasma enhanced chemical vapor deposition, will result in the transition metal doping of semiconducting boron carbides. Here we report using ferrocene to introduce Fe dop¬ants, and a semiconducting boron-carbide homojunction has been fabricated. The diode characteristics are very similar to those fabricated with Co and Ni doping.


Quantitative Analyses Of Dispersion, Doping And Electronic Separation Of Single Wall Hipco Carbon Nanotubes, Priya Baskar Rao Jan 2009

Quantitative Analyses Of Dispersion, Doping And Electronic Separation Of Single Wall Hipco Carbon Nanotubes, Priya Baskar Rao

Doctoral

As prepared SWNTs are obtained in bundles with a mixture of both metallic and semi conducting tubes. For many specific applications, electronically separated single individual tubes are required and in order to reach these application criteria, the tubes should be processed. This thesis reports on a systematic exploration of methods to routinely process, electronically separate and characterise commercially available single walled carbon nanotubes (SWNTs). Commercially available HiPco SWNTs were dispersed in water with the assistance of 1 % by weight sodium dodecyl benzene sulphate (SDBS). The tubes were dispersed in the water surfactant system through the aid of sonication and …