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Full-Text Articles in Physics

Mononuclear N3S(Thioether)-Ligated Copper(Ii) Methoxide Complexes: Synthesis, Characterization, And Hydrolytic Reactivity, Kyle J. Tubbs, Amy L. Fuller, Brian Bennett, Atta M. Arif, Lisa M. Berreau Aug 2003

Mononuclear N3S(Thioether)-Ligated Copper(Ii) Methoxide Complexes: Synthesis, Characterization, And Hydrolytic Reactivity, Kyle J. Tubbs, Amy L. Fuller, Brian Bennett, Atta M. Arif, Lisa M. Berreau

Physics Faculty Research and Publications

Mononuclear copper(II) methoxide complexes supported by N3S(thioether) chelate ligands having two internal hydrogen bond donors have been prepared, comprehensively characterized, and evaluated for hydrolytic reactivity.


Photofragmentation Dynamics Of Core-Excited Water By Anion-Yield Spectroscopy, Wayne C. Stolte, M. M. Sant'anna, Gunnar Ohrwall, Maria Novella Piancastelli, I. Dominguez-Lopez, Dennis W. Lindle Aug 2003

Photofragmentation Dynamics Of Core-Excited Water By Anion-Yield Spectroscopy, Wayne C. Stolte, M. M. Sant'anna, Gunnar Ohrwall, Maria Novella Piancastelli, I. Dominguez-Lopez, Dennis W. Lindle

Chemistry and Biochemistry Faculty Research

Partial-anion and- cation yields from H2O are presented for photon energies near the oxygen K edge. The O- yield exhibits a feature above threshold attributed to doubly excited states, in contrast to the H- and cation yields, which are nearly featureless above threshold. Additionally, the lack of the OH- fragment indicates radiative decay and provides a negligible amount of anion formation.