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Metastable Anions Of Dinitrobenzene: Resonances For Electron Attachment And Kinetic Energy Release, A. Mauracher, S. Denifl, A. Edtbauer, M. Hager, M. Probst, Olof E. Echt, T. D. Maerk, P. Scheier, T. A. Field, K. Graupner
Metastable Anions Of Dinitrobenzene: Resonances For Electron Attachment And Kinetic Energy Release, A. Mauracher, S. Denifl, A. Edtbauer, M. Hager, M. Probst, Olof E. Echt, T. D. Maerk, P. Scheier, T. A. Field, K. Graupner
Physics & Astronomy
Attachment of free, low-energy electrons to dinitrobenzene (DNB) in the gas phase leads to DNB as well as several fragment anions. DNB, (DNB-H), (DNB-NO), (DNB-2NO), and (DNB-NO(2)) are found to undergo metastable (unimolecular) dissociation. A rich pattern of resonances in the yield of these metastable reactions versus electron energy is observed; some resonances are highly isomer-specific. Most metastable reactions are accompanied by large average kinetic energy releases (KER) that range from 0.5 to 1.32 eV, typical of complex rearrangement reactions, but (1,3-DNB-H)(-) features a resonance with a KER of only 0.06 eV for loss of NO. (1,3-DNB-NO)(-) offers a rare …
Lifetimes Of C-60(2-) And C-70(2-) Dianions In A Storage Ring, S. Tomita, J. U. Andersen, H. Cederquist, B. Concina, Olof E. Echt, J. S. Forster, K. Hansen, B. A. Huber, P. Hvelplund, J. Jensen, B. Liu, B. Manil, L. Maunoury
Lifetimes Of C-60(2-) And C-70(2-) Dianions In A Storage Ring, S. Tomita, J. U. Andersen, H. Cederquist, B. Concina, Olof E. Echt, J. S. Forster, K. Hansen, B. A. Huber, P. Hvelplund, J. Jensen, B. Liu, B. Manil, L. Maunoury
Physics & Astronomy
C-60(2-) and C-70(2-) dianions have been produced by electrospray of the monoanions and subsequent electron pickup in a Na vapor cell. The dianions were stored in an electrostatic ring and their decay by electron emission was measured up to 1 s after injection. While C-70(2-) ions are stable on this time scale, except for a small fraction of the ions which have been excited by gas collisions, most of the C-60(2-) ions decay on a millisecond time scale, with a lifetime depending strongly on their internal temperature. The results can be modeled as decay by electron tunneling through a Coulomb …
Mechanisms And Dynamics Of The Metastable Decay In Ar-2(+), J. Fedor, K. Gluch, R. Parajuli, S. Matt-Leubner, Olof E. Echt, P. Scheier, T. D. Mark
Mechanisms And Dynamics Of The Metastable Decay In Ar-2(+), J. Fedor, K. Gluch, R. Parajuli, S. Matt-Leubner, Olof E. Echt, P. Scheier, T. D. Mark
Physics & Astronomy
A detailed experimental as well as theoretical investigation of the properties of the metastable dissociation Ar-2(+)-->Ar++Ar is presented. The mass-analyzed ion kinetic energy (MIKE) scan technique has been performed using a three sector field mass spectrometer. The possible mechanisms of the metastability of Ar-2(+) have been examined and the observed decay process is assigned to the II(1/2)(u)-->I(1/2)(g) bound to continuum radiative transition, in agreement with earlier work. The calculation of the theoretical shape of the kinetic energy release distribution of fragment ions allowed us to construct the theoretical MIKE peak and compare it with the raw experimental data. …