Physics Commons^™

Microscopic-Macroscopic Simulations Of Rigid-Rod Polymer Hydrodynamics: Heterogeneity And Rheochaos, M. Gregory Forest, Ruhai Zhou, Qi Wang

Mathematics & Statistics Faculty Publications

Rheochaos is a remarkable phenomenon of nematic (rigid-rod) polymers in steady shear, with sustained chaotic fluctuations of the orientational distribution of the rod ensemble. For monodomain dynamics, imposing spatial homogeneity and linear shear, rheochaos is a hallmark prediction of the Doi-Hess theory [M. Doi, J. Polym. Sci. Polym. Phys. Ed., 19 (1981), pp. 229-243; M. Doi and S. F. Edwards, The Theory of Polymer Dynamics, Oxford University Press, London, New York, 1986; S. Hess, Z. Naturforsch., 31 (1976), pp. 1034-1037. The model behavior is robust, captured by second-moment tensor approximations G. Rienäcker, M. Kröger, and S. Hess, Phys. Rev. …