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Evgeny Tsymbal Publications

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First-principles

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Full-Text Articles in Physics

Giant Enhancement Of Magnetic Anisotropy In Ultrathin Manganite Films Via Nanoscale 1d Periodic Depth Modulation, Anil Rajapitamahuni, L. Zhang, Mark A. Koten, V. R. Singh, John D. Burton, Evgeny Y. Tsymbal, Jeffrey E. Shield, Xia Hong May 2016

Giant Enhancement Of Magnetic Anisotropy In Ultrathin Manganite Films Via Nanoscale 1d Periodic Depth Modulation, Anil Rajapitamahuni, L. Zhang, Mark A. Koten, V. R. Singh, John D. Burton, Evgeny Y. Tsymbal, Jeffrey E. Shield, Xia Hong

Evgeny Tsymbal Publications

The relatively low magnetocrystalline anisotropy (MCA) in strongly correlated manganites (La,Sr)MnO3 has been a major hurdle for implementing them in spintronic applications. Here we report an unusual, giant enhancement of in-plane MCA in 6 nm La0.67Sr0.33MnO3 (LSMO) films grown on (001) SrTiO3 substrates when the top 2 nm is patterned into periodic stripes of 100 or 200 nm width. Planar Hall effect measurements reveal an emergent uniaxial anisotropy superimposed on one of the original biaxial easy axes for unpatterned LSMO along (110) directions, with a 50-fold enhanced anisotropy energy density of 5.6 × …


Hydroxyl-Decorated Graphene Systems As Candidates For Organic Metal-Free Ferroelectrics, Multiferroics, And High-Performance Proton Battery Cathode Materials, Menghao Wu, John D. Burton, Evgeny Y. Tsymbal, Xiao Cheng Zeng, Purusottam Jena Feb 2013

Hydroxyl-Decorated Graphene Systems As Candidates For Organic Metal-Free Ferroelectrics, Multiferroics, And High-Performance Proton Battery Cathode Materials, Menghao Wu, John D. Burton, Evgeny Y. Tsymbal, Xiao Cheng Zeng, Purusottam Jena

Evgeny Tsymbal Publications

Using a first-principles method we show that graphene based materials, functionalized with hydroxyl groups, constitute a class of multifunctional, lightweight, and nontoxic organic materials with functional properties such as ferroelectricity, multiferroicity, and can be used as proton battery cathode materials. For example, the polarizations of semihydroxylized graphane and graphone, as well as fully hydroxylized graphane, are much higher than any organic ferroelectric materials known to date. Further, hydroxylized graphene nanoribbons with proton vacancies at the end can have much larger dipole moments. They may also be applied as high-capacity cathode materials with a specific capacity that is six times larger …