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Department of Physics and Astronomy: Faculty Publications

Thin films

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The Influence Of The Substrate On The Functionality Of Spin Crossover Molecular Materials, Saeed Yazdani, Jared Phillips, Thilini K. Ekanayaka, Ruihua Cheng, Peter A. Dowben Apr 2023

The Influence Of The Substrate On The Functionality Of Spin Crossover Molecular Materials, Saeed Yazdani, Jared Phillips, Thilini K. Ekanayaka, Ruihua Cheng, Peter A. Dowben

Department of Physics and Astronomy: Faculty Publications

Spin crossover complexes are a route toward designing molecular devices with a facile readout due to the change in conductance that accompanies the change in spin state. Because substrate effects are important for any molecular device, there are increased efforts to characterize the influence of the substrate on the spin state transition. Several classes of spin crossover molecules deposited on different types of surface, including metallic and non-metallic substrates, are comprehensively reviewed here. While some non-metallic substrates like graphite seem to be promising from experimental measurements, theoretical and experimental studies indicate that 2D semiconductor surfaces will have minimum interaction with …