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Full-Text Articles in Physics
Robust, Bridge-Less Ion-Selective Electrodes With Significantly Reduced Need For Pre- And Post-Application Handling, Benjamin Schazmann, S. Demey, Z. Waqar Ali, M-S Plissart, E. Brennan, A. Radu
Robust, Bridge-Less Ion-Selective Electrodes With Significantly Reduced Need For Pre- And Post-Application Handling, Benjamin Schazmann, S. Demey, Z. Waqar Ali, M-S Plissart, E. Brennan, A. Radu
Articles
We are demonstrating robust, single-layer ion-selective electrode (ISE) utilizing simple Ag/AgCl electrode as solid support without the need for intermediate polymer layer. We have created and chemically linked a family of imidazolium ionic liquids (ILs) with poly (vinyl chloride) (PVC) using click chemistry, resulting in hybrid materials with tunable characteristics. The resultant material inherently contains chloride ion thus offering the ability to stabilize interfacial potential. This allowed us to construct very simple, single-layer membranes with significantly reduced need for conditioning as an added bonus compared to traditional sensors. Chemical immobilization of ISE membrane components also led to extended lifetime as …
Self-Processing Photopolymer Materials For Versatile Design And Fabrication Of Holographic Sensors And Interactive Holograms, Dervil Cody, Sabad-E Gul, Tatsiana Mikulchyk, Muhammad Irfan, Anastasia Kharchenko, Kamila Goldyn, Suzanne Martin, Svetlana Mintova, John Cassidy, Izabela Naydenova
Self-Processing Photopolymer Materials For Versatile Design And Fabrication Of Holographic Sensors And Interactive Holograms, Dervil Cody, Sabad-E Gul, Tatsiana Mikulchyk, Muhammad Irfan, Anastasia Kharchenko, Kamila Goldyn, Suzanne Martin, Svetlana Mintova, John Cassidy, Izabela Naydenova
Articles
The aim of this paper is to discuss the benefits as well as the limitations of utilizing photopolymer materials in the design of holograms that are responsive to changes in their environment, such as changes in the concentration of a specific substance, temperature, and pressure. Three different case studies are presented, including both surface and volume phase holograms, in order to demonstrate the flexibility in the approach of utilizing holographic photopolymers for the design of sensors and interactive optical devices. First, a functionalized surface relief hologram is demonstrated to operate as an optical sensor for the detection of metal ions …
Theoretical Modeling And Design Of Photonic Structures In Zeolite Nanocomposites For Gas Sensing. Part Ii: Volume Gratings, Dervil Cody, Izabela Naydenova
Theoretical Modeling And Design Of Photonic Structures In Zeolite Nanocomposites For Gas Sensing. Part Ii: Volume Gratings, Dervil Cody, Izabela Naydenova
Articles
The suitability of holographic structures fabricated in zeolite nanoparticle-polymer composite materials for gas sensing applications has been investigated. Theoretical modelling of the sensor response (i.e. change in hologram readout due to a change in refractive index modulation or thickness as a result of gas adsorption) of different sensor designs was carried out using Raman-Nath theory and Kogelnik’s Coupled Wave Theory. The influence of a range of parameters on the sensitivity of holographically-recorded surface and volume photonic structures has been studied, namely hologram geometry, hologram thickness and spatial frequency, reconstruction wavelength, and zeolite nanoparticle refractive index. From this, the optimum fabrication …
N-Isopropylacrylamide-Based Photopolymer For Holographic Recording Of Thermosensitive Transmission And Reflection Grating, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova
N-Isopropylacrylamide-Based Photopolymer For Holographic Recording Of Thermosensitive Transmission And Reflection Grating, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova
Articles
In recent years, functionalized photopolymer systems capable of holographic recording are in great demand due to their potential use in the development of holographic sensors. This work presents a newly developed Nisopropylacrylamide(NIPA)-based photopolymer for holographic recording in reflection and transmission modes. The optimized composition of the material is found to reach refractive index modulation of up to 5 10-3 and 1.6 10-3 after recording in transmission and reflection mode, respectively. In addition to fulfilling the requirements for holographic recording materials, the NIPA-based photopolymer is sensitive to temperature and has lower toxicity than acrylamide-based photopolymers. Possible application of the …
Microfiber Coupler Based Label-Free Immunosensor, Lin Bo, Christy Charlton O'Mahony, Yuliya Semenova, Niamh Gilmartin, Pengfei Wang, Gerald Farrell
Microfiber Coupler Based Label-Free Immunosensor, Lin Bo, Christy Charlton O'Mahony, Yuliya Semenova, Niamh Gilmartin, Pengfei Wang, Gerald Farrell
Articles
Optical microfibers and related structures which incorporate large evanescent field and minimal size offer new opportunities for biosensing applications. In this paper we report the development of an immunosensor based on a tapered microfiber coupler embedded in a low refractive index polymer. Biomolecules adsorbed on the microfiber coupler surface modify the surrounding refractive index. By immobilizing antigens on the surface of the sensing area, the microfiber coupler was able to operate as a label-free immunosensor to detect specific antibodies. We experimentally demonstrated for the first time the sensing ability of this sensor using a fibrinogen antigen-antibody pair. By monitoring the …
Research On Holographic Sensors And Novel Photopolymers At The Centre For Industrial And Egnineering Optics, Emilia Mihaylova, Dervil Cody, Izabela Naydenova, Suzanne Martin, Vincent Toal
Research On Holographic Sensors And Novel Photopolymers At The Centre For Industrial And Egnineering Optics, Emilia Mihaylova, Dervil Cody, Izabela Naydenova, Suzanne Martin, Vincent Toal
Books/Book Chapters
The recent resurgence of interest in photopolymers for commercial holograms is a strong incentive for development of photopolymers that are as environmentally friendly as possible. Photopolymer materials consist of a light-sensitive film which is exposed during production to form the hologram, thereby offering versatility well beyond that of current security holograms, which are mass produced from a master using a foil stamping processes.
Recent And Emerging Applications Of Holographic Photopolymers And Nanocomposites, Izabela Naydenova, Pavani Kotakonda, Raghavendra Jallapuram, Tsvetanka Babeva, Denis Bade, Suzanne Martin, Vincent Toal, Svetlana Mintova
Recent And Emerging Applications Of Holographic Photopolymers And Nanocomposites, Izabela Naydenova, Pavani Kotakonda, Raghavendra Jallapuram, Tsvetanka Babeva, Denis Bade, Suzanne Martin, Vincent Toal, Svetlana Mintova
Conference Papers
Sensing applications of holograms may be based on effects such as change in the spacing of the recorded fringes in a holographic diffraction grating in the presence of an analyte so that the direction of the diffracted laser light changes, or, in the case of a white light reflection grating, the wavelength of the diffracted light changes. An example is a reflection grating which swells in the presence of atmospheric moisture to indicate relative humidity by a change is the colour of the diffracted light. These devices make use of the photopolymer’s ability to absorb moisture. In a more versatile …