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Optical Characterization Of The Nematic Lyotropic Chromonic Liquid Crystals: Light Absorption, Birefringence, And Scalar Order Parameter, Yuriy A. Nastishin, H. Liu, T. Schneider, V. G. Nazarenko, Sergij V. Shiyanovskii, Oleg Lavrentovich
Optical Characterization Of The Nematic Lyotropic Chromonic Liquid Crystals: Light Absorption, Birefringence, And Scalar Order Parameter, Yuriy A. Nastishin, H. Liu, T. Schneider, V. G. Nazarenko, Sergij V. Shiyanovskii, Oleg Lavrentovich
Oleg Lavrentovich
We report on the optical properties of the nematic (N) phase formed by lyotropic chromonic liquid crystals (LCLCs) in well aligned planar samples. LCLCs belong to a broad class of materials formed by one-dimensional molecular self-assembly and are similar to other systems such as “living polymers” and “wormlike micelles.” We study three water soluble LCLC forming materials: disodium chromoglycate, a derivative of indanthrone called Blue 27, and a derivative of perylene called Violet 20. The individual molecules have a planklike shape and assemble into rodlike aggregates that form the N phase once the concentration exceeds about 0.1M. The uniform surface …
Self-Assembly, Condensation, And Order In Aqueous Lyotropic Chromonic Liquid Crystals Crowded With Additives, Luana Tortora, Heung-Shik Park, Shin-Woong Kang, Victoria Savaryn, Seung-Ho Hong, Konstantine Kaznatcheev, Daniele Finotello, Samuel Sprunt, Satyendra Kumar, Oleg Lavrentovich
Self-Assembly, Condensation, And Order In Aqueous Lyotropic Chromonic Liquid Crystals Crowded With Additives, Luana Tortora, Heung-Shik Park, Shin-Woong Kang, Victoria Savaryn, Seung-Ho Hong, Konstantine Kaznatcheev, Daniele Finotello, Samuel Sprunt, Satyendra Kumar, Oleg Lavrentovich
Oleg Lavrentovich
Dense multicomponent systems with macromolecules and small solutes attract a broad research interest as they mimic the molecularly crowded cellular interiors. The additives can condense and align the macromolecules, but they do not change the degree of covalentpolymerization. We chose a lyotropic chromonic liquid crystal with reversibly and non-covalently assembled aggregates as a much softer system, reminiscent of “living polymers”, to demonstrate that small neutral and charged additives cause condensation of aggregates with ensuing orientational and positional ordering and nontrivial morphologies of phase separation, such as tactoids and toroids of the nematic and hexagonal columnar phase coexisting with the isotropic …