Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Physics
Resonant Plasmonic–Biomolecular Chiral Interactions In The Far-Ultraviolet: Enantiomeric Discrimination Of Sub-10 Nm Amino Acid Films, Tiago Ramos Leite, Lin Zschiedrich, Orhan Kizilkaya, Kevin M. Mcpeak
Resonant Plasmonic–Biomolecular Chiral Interactions In The Far-Ultraviolet: Enantiomeric Discrimination Of Sub-10 Nm Amino Acid Films, Tiago Ramos Leite, Lin Zschiedrich, Orhan Kizilkaya, Kevin M. Mcpeak
Faculty Publications
Resonant plasmonic–molecular chiral interactions are a promising route to enhanced biosensing. However, biomolecular optical activity primarily exists in the far-ultraviolet regime, posing significant challenges for spectral overlap with current nano-optical platforms. We demonstrate experimentally and computationally the enhanced chiral sensing of a resonant plasmonic–biomolecular system operating in the far-UV. We develop a full-wave model of biomolecular films on Al gammadion arrays using experimentally derived chirality parameters. Our calculations show that detectable enhancements in the chiroptical signals from small amounts of biomolecules are possible only when tight spectral overlap exists between the plasmonic and biomolecular chiral responses. We support this conclusion …
Connecting Ansatz Expressibility To Gradient Magnitudes And Barren Plateaus, Zoe Holmes, Kunal Sharma, M Cerezo, Patrick Coles
Connecting Ansatz Expressibility To Gradient Magnitudes And Barren Plateaus, Zoe Holmes, Kunal Sharma, M Cerezo, Patrick Coles
Faculty Publications
Parametrized quantum circuits serve as ansatze for solving variational problems and provide a flexible paradigm for the programming of near-term quantum computers. Ideally, such ansatze should be highly expressive, so that a close approximation of the desired solution can be accessed. On the other hand, the ansatz must also have sufficiently large gradients to allow for training. Here, we derive a fundamental relationship between these two essential properties: expressibility and trainability. This is done by extending the well-established barren plateau phenomenon, which holds for ansatze that form exact 2-designs, to arbitrary ansatze. Specifically, we calculate the variance in the cost …
Towards A Quantum Notion Of Covariance In Spherically Symmetric Loop Quantum Gravity, Rodolfo Gambini, Javier Olmedo, Jorge Pullin
Towards A Quantum Notion Of Covariance In Spherically Symmetric Loop Quantum Gravity, Rodolfo Gambini, Javier Olmedo, Jorge Pullin
Faculty Publications
The covariance of loop quantum gravity studies of spherically symmetric space-times has recently been questioned. This is a reasonable worry, given that they are formulated in terms of slicing-dependent variables. We show explicitly that the resulting space-times, obtained from Dirac observables of the quantum theory, are covariant in the usual sense of the way-they preserve the quantum line element-for any gauge that is stationary (in the exterior, if there is a horizon). The construction depends crucially on the details of the Abelianized quantization considered, the satisfaction of the quantum constraints, and the recovery of standard general relativity in the classical …