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Full-Text Articles in Physics

Nanoscale Hybrid Electrolytes With Viscosity Controlled Using Ionic Stimulus For Electrochemical Energy Conversion And Storage, Sara T. Hamilton, Tony G. Feric, Sahana Bhattacharyya, Nelly M. Cantillo, Steven G. Greenbaum, Thomas A. Zawodzinski, Ah-Hyung Alissa Park Mar 2022

Nanoscale Hybrid Electrolytes With Viscosity Controlled Using Ionic Stimulus For Electrochemical Energy Conversion And Storage, Sara T. Hamilton, Tony G. Feric, Sahana Bhattacharyya, Nelly M. Cantillo, Steven G. Greenbaum, Thomas A. Zawodzinski, Ah-Hyung Alissa Park

Publications and Research

As renewable energy is rapidly integrated into the grid, the challenge has become storing intermittent renewable electricity. Technologies including flow batteries and CO 2 conversion to dense energy carriers are promising storage options for renewable electricity. To achieve this technological advancement, the development of next generation electrolyte materials that can increase the energy density of flow batteries and combine CO 2 capture and conversion is desired. Liquid-like nanoparticle organic hybrid materials (NOHMs) composed of an inorganic core with a tethered polymeric canopy (e.g., polyetheramine (HPE)) have a capability to bind chemical species of interest including CO 2 and redox-active species. …


The Advection-Diffusion Equation And The Enhanced Dissipation Effect For Flows Generated By Hamiltonians, Michael Kumaresan May 2018

The Advection-Diffusion Equation And The Enhanced Dissipation Effect For Flows Generated By Hamiltonians, Michael Kumaresan

Dissertations, Theses, and Capstone Projects

We study the Cauchy problem for the advection-diffusion equation when the diffusive parameter is vanishingly small. We consider two cases - when the underlying flow is a shear flow, and when the underlying flow is generated by a Hamiltonian. For the former, we examine the problem on a bounded domain in two spatial variables with Dirichlet boundary conditions. After quantizing the system via the Fourier transform in the first spatial variable, we establish the enhanced-dissipation effect for each mode. For the latter, we allow for non-degenerate critical points and represent the orbits by points on a Reeb graph, with vertices …


Classical Transport In Disordered Systems, Antonios Papaioannou Jun 2016

Classical Transport In Disordered Systems, Antonios Papaioannou

Dissertations, Theses, and Capstone Projects

This thesis reports on the manifestation of structural disorder on molecular transport and it consists of two parts. Part I discusses the relations between classical transport and the underlying structural complexity of the system. Both types of molecular diffusion, namely Gaussian and non-Gaussian are presented and the relevant time regimes are discussed. In addition the concept of structural universality is introduced and connected with the diffusion metrics. One of the most robust techniques for measuring molecular mean square displacements is magnetic resonance. This method requires encoding and subsequently reading out after an experimentally controlled time, a phase ϕ to the …