Physics Commons^™

Dative Epitaxy Of Commensurate Monocrystalline Covalent Van Der Waals Moiré Supercrystal, Mengying Bian, Liang Zhu, Xiao Wang, Junho Choi, Rajesh V. Chopdekar, Sichen Wei, Lishu Wu, Chang Huai, Austin Marga, Qishuo Yang, Yuguang C. Li, Fei Yao, Ting Yu, Scott A. Crooker National High Magnetic Field Laboratory, Los Alamos National Laboratory, Xuemei Cheng, Renat F. Sabirianov, Shengbai Zhang, Junhao Lin, Yanglong Hou, Hao Zeng

Physics Faculty Research and Scholarship

Realizing van der Waals (vdW) epitaxy in the 1980s represents a breakthrough that circumvents the stringent lattice matching and processing compatibility requirements in conventional covalent heteroepitaxy. However, due to the weak vdW interactions, there is little control over film qualities by the substrate. Typically, discrete domains with a spread of misorientation angles are formed, limiting the applicability of vdW epitaxy. Here, the epitaxial growth of monocrystalline, covalent Cr5Te8 2D crystals on monolayer vdW WSe2 by chemical vapor deposition is reported, driven by interfacial dative bond formation. The lattice of Cr5Te8, with a lateral dimension of a few tens of micrometers, …