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Investigation Of Optical Spectroscopy Techniques For On-Line Materials Accountability In The Solvent Extraction Process, Gary Cerefice, Kenneth Czerwinski Jan 2007

Investigation Of Optical Spectroscopy Techniques For On-Line Materials Accountability In The Solvent Extraction Process, Gary Cerefice, Kenneth Czerwinski

Safeguards Campaign (TRP)

The goal of this project is to evaluate the application of these analytical techniques to the on-line, real-time measurement of the actinide elements in the process streams of a solvent extraction process, with particular attention to the UREX+ and PUREX processes. Based on the experience gained through this effort, engineers will have the information necessary to decide if these technologies should be advanced to the prototype stage and tested at the pilot plant level. Through the experimental work planned as part of this effort, researchers will also develop a better understanding of the chemical interactions of the actinide elements, providing …


Preparation Studies For Secondary Electron Emission Experiments On Superconducting Niobium, Anoop George, Robert A. Schill Jr. Mar 2004

Preparation Studies For Secondary Electron Emission Experiments On Superconducting Niobium, Anoop George, Robert A. Schill Jr.

Transmutation Sciences Materials (TRP)

Accelerator driven transmutation of waste is one complementary approach to deal with spent nuclear fuel as compared to permanent storage. High-energy protons generated by a particle accelerator collide with a heavy metal target producing neutrons. Long-lived radioactive isotopes interacting with the neutrons transmute into shorter-lived isotopes. To generate the high-energy protons efficiently, linear accelerators use multi-cell superconducting radio frequency (RF) cavities made of niobium. Superconducting niobium cavities have several advantages, including small power dissipation. The high electromagnetic fields present in these cavities may result in undesired field emission from surface imperfections with the probability of generating an avalanche of secondary …


Investigation Of Optical Spectroscopy Techniques For On-Line Materials Accountability In The Solvent Extraction Process, Gary Cerefice, Kenneth Czerwinski Jan 2004

Investigation Of Optical Spectroscopy Techniques For On-Line Materials Accountability In The Solvent Extraction Process, Gary Cerefice, Kenneth Czerwinski

Safeguards Campaign (TRP)

The goal of this project is to examine the potential for using optical spectroscopy techniques, such as UV-Visible Spectroscopy and Laser Fluorescence Spectroscopy, for special nuclear materials accountability applications for the UREX+ and other solvent extraction processes. To increase the inherent proliferation resistance of the solvent extraction process, it is necessary to develop on-line techniques to directly measure the concentrations of special nuclear materials in-process. By providing on-line materials accountability for the processes, the potential for covert diversion of the materials streams becomes much more difficult to implement. On-line monitoring of material streams will also allow for improved plant operation, …