Physics Commons^™

Measuring The Practical Particle-In-A-Box: Orthorhombic Perovskite Nanocrystals, Brandon Mitchell, Eric Herrmann, Junhao Lin, Leyre Gomez, Chris De Weerd, Yasufumi Fujiwara, Kazutomo Suenaga, Tom Gregorkiewicz

Physics & Engineering Faculty Publications

A connection between condensed matter physics and basic quantum mechanics is demonstrated as we use the fundamental 3D particle-in-a-box model to explain the optical properties of semiconductor nanocrystals, which are substantially modified due to quantum confinement. We also discuss recent advances in the imaging and measurement capabilities of transmission electron microscopy, which have made it possible to directly image single nanocrystals while simultaneously measuring their characteristic absorption energies. We introduce the basic theory of nanocrystals and derive a simplified expression to approximate the optical bandgap energy of an orthorhombic nanocrystal. CsPbBr3 perovskite nanocrystals are used to demonstrate this model due …