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Full-Text Articles in Physics
Enhanced Quantum Dot Emission For Luminescent Solar Concentrators Using Plasmonic Interaction, Subhash Chandra, Manus Kennedy, John Doran, Sarah Mccormack, A. J. Chatten
Enhanced Quantum Dot Emission For Luminescent Solar Concentrators Using Plasmonic Interaction, Subhash Chandra, Manus Kennedy, John Doran, Sarah Mccormack, A. J. Chatten
Articles
Plasmonic excitation enhanced fluorescence of CdSe/ZnS core-shell quantum dots (QDs) in the presence of Au nanoparticles (NPs) has been studied for application in quantum dot solar concentrator (QDSC) devices. We observe that there is an optimal concentration of Au NPs that gives a maximum 53% fluorescence emission enhancement for the particular QD/Au NP composite studied. The optimal concentration depends on the coupling and spacing between neighboring QDs and Au NPs. We show the continuous transition from fluorescence enhancement to quenching, depending on Au NP concentration. The locally enhanced electromagnetic field induced by the surface plasmon resonance in the Au NPs …
Solutions To Quasi-Relativistic Multi-Configurative Hartree-Fock Equations In Quantum Chemistry, Carlos Argáez García, Michael Melgaard
Solutions To Quasi-Relativistic Multi-Configurative Hartree-Fock Equations In Quantum Chemistry, Carlos Argáez García, Michael Melgaard
Articles
We establish existence of infinitely many distinct solutions to the multi-configurative Hartree-Fock type equations for N-electron Coulomb systems with quasi-relativistic kinetic energy for the n th electron. Finitely many of the solutions are interpreted as excited states of the molecule. Moreover, we prove existence of a ground state. The results are valid under the hypotheses that the total charge Z of K nuclei is greater than N-1 and that Z is smaller than a critical charge. The proofs are based on a new application of the Lions-Fang-Ghoussoub critical point approach to nonminimal solutions on a complete analytic Hilbert-Riemann manifold.
Fluorescence Emission Study Of Cdse/Zns Quantum Dot And Au Nanoparticles Composite For Application In Quantum Dot Solar Concentrators, Subhash Chandra, John Doran, Manus Kennedy, S Mccormack, A Chatten
Fluorescence Emission Study Of Cdse/Zns Quantum Dot And Au Nanoparticles Composite For Application In Quantum Dot Solar Concentrators, Subhash Chandra, John Doran, Manus Kennedy, S Mccormack, A Chatten
Conference Papers
Fluorescence of core shell (CdSe/ZnS) quantum dots (QDs) and Au nanoparticles (NPs) composite has been studied for application in quantum dot solar concentrators (QDSC). We conclude two points from the particular QD/Au NP composite studied. One; for the particular Au NPs concentration, the relative fluorescence emission enhancement increases with decreasing QD concentration. Second; the enhancement is more pronounced for the Au nanoparticles whose surface plasmon resonance wavelength overlaps with the absorption peak of QDs. The fundamental concept that could describe the change in fluorescence emission of QDs in the presence of Au NPs is the locally enhanced electromagnetic field induced …