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Plasma and Beam Physics

Air Force Institute of Technology

Chemical kinetics

Publication Year

Articles 1 - 3 of 3

Full-Text Articles in Physics

Analysis Of Ar(1s5) Metastable Populations In High Pressure Argon-Helium Gas Discharges, Daniel J. Emmons Ii Sep 2017

Analysis Of Ar(1s5) Metastable Populations In High Pressure Argon-Helium Gas Discharges, Daniel J. Emmons Ii

Theses and Dissertations

Simulations of an argon-helium plasma are performed for two high pressure discharge scenarios to find a uniform, large-volume plasma with Ar(1s5) metastable densities on the order of 1013 cm-3 for use as the ground state in an optically pumped rare gas laser. An analysis of a pulsed direct current discharge is performed for a 7% argon in helium mixture at a pressure of 270 Torr using both zero and one-dimensional models. Kinetics of species relevant to the operation of an optically pumped rare gas laser are analyzed throughout the pulse duration to identify key reaction pathways. Simulations are …


Kinetics Of The Electrical Discharge Pumped Oxygen-Iodine Laser, Matthew A. Lange Dec 2011

Kinetics Of The Electrical Discharge Pumped Oxygen-Iodine Laser, Matthew A. Lange

Theses and Dissertations

A systematic study of microwave discharges at 2.45 GHz has been performed through the pressure range of sustainable electric discharges in pure oxygen flows of 2 to 10 Torr. A corresponding study of 13.56 MHz has also been performed at pressures of 2, 4, and 7 Torr. Optical emissions from O2(a 1Δ), O2(b 1Σ), and O-atoms have been measured from the center of a μ-wave discharge. Discharge residence times from 0.1 to 5 ms have been reported. The O2(b 1Σ) emissions, with a spectral resolution of 0.01 nm, have been used to measure the temperature of the gas, which typically …


The Kinetics Following Photolysis Of Nitrosyl Bromide, Lori A. Mahoney Dec 2004

The Kinetics Following Photolysis Of Nitrosyl Bromide, Lori A. Mahoney

Theses and Dissertations

One candidate for the development of a tunable laser in the mid-infrared for use as a defensive countermeasure against passive sensors exploits the nitric oxide (NO) transition at 5.4 μm. However, the difficulty with this mechanism is that when bromine (Br2) and NO are present in a mixture, nitrosyl bromide (BrNO) is also created. The absorption bands present in BrNO complicate the design of such a laser. This thesis determines the forward and reverse rate constants of the reaction of Br2 and NO to form BrNO following the photolysis of BrNO using Fourier Transform Infrared absorption spectroscopy. …