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Physical Chemistry

University of Nevada, Las Vegas

2016

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Structural Behavior Of Nbsexte2-X Superconductors Under High Pressure, Vahe Mkrtchyan Aug 2016

Structural Behavior Of Nbsexte2-X Superconductors Under High Pressure, Vahe Mkrtchyan

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Niobium chalcogenide compounds have recently gained a great deal of interest due to the fact that a superconducting phase coexists with the charge density wave state (CDW), as well as their potential for numerous applications. Two superconducting compositions, NbSexTe2-x (x=2, 1.5) were prepared by solid state route using high purity Nb, Se, and Te powders. Powder X-ray diffraction patterns collected at ambient conditions for NbSe2 and NbSe1.5Te0.5 showed a single phase with hexagonal crystal structure, with space group P63mmc. High-pressure X-ray diffraction measurements were performed at the Advanced Photon Source at Argonne National Laboratory to investigate structural stability up to …