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Investigation Of Potential Oxygen Defect Mechanism Of Persistent Photoconductivity And Photoinduced Superconductivity In Yba2cu3ox, Denise Catherine Chew

Theses

In this thesis work, we conclude that oxygen vacancy defects play a fundamental role in the PPC/PISC mechanism and identify the oxygen defects as F centers (an oxygen vacancy which traps two electrons) or F⁺ centers. Also, the correlation between the peaks observed in the luminescence spectra and those observed in the wavelength dependence of PPC suggest that the photogeneration of charges and their annihilation via luminescent recombination occur in the same level (Cu-O chains) of the YBa₂Cu₃O_x crystal. Previous models had assigned the peaks in the PPC excitation spectrum to charge transfer in …