Physics Commons^™

Synthesis, Characterization, And Simulation Of Two-Dimensional Materials, Lawrence Hudy

Theses and Dissertations

ABSTRACT

SYNTHESIS, CHARACTERIZATION, AND SIMULATION OF TWO-DIMENSIONAL MATERIALS

by

Lawrence Hudy

The University of Wisconsin-Milwaukee, 2023Under the Supervision of Professor Michael Weinert

This dissertation focuses on my journey through many aspects of surface science leading to the first principles investigation of transition metal dichalcogenides studying the impact of defects, twist, and decreasing interlayer separation to probe their effect on the electronic properties of these materials. My journey started out learning many aspects of material science such as methods for material synthesis and characterization but later ended on simulation of material properties using density functional theory. In the first experiments, we …

Dyonic Taub-Nut-Ads Space Phase Structure, Mohamed Tharwat

Theses and Dissertations

The Taub-NUT spacetime remains to hold many mysteries more than half a century after its discovery. The metric's controversy owes largely to the nut charge and the existence of Misner strings. Traditionally the metric is treated in the euclidean signature, this treatment hides the Misner strings. We treat the Taub-NUT spacetime with the Misner strings visible, not enforcing the time periodicity condition. We examine the phase structure belonging to three different horizon geometries. We deal with the hyperbolic, flat and spherical cases. We consider the stable phases, the phase transitions that exist between them, and find the preferable phases in …

Quantum Error Detection Without Using Ancilla Qubits, Nicolas Guerrero

Theses and Dissertations

Quantum computers are beset by errors from a variety of sources. Although quantum error correction and detection codes have been developed since the 1990s, these codes require mid-circuit measurements in order to operate. In order to avoid these measurements we have developed a new error detection code that only requires state collapses at the end of the circuit, which we call no ancilla error detection (NAED). We investigate some of the mathematics behind NAED such as which codes can detect which errors. We then run NAED on three separate types of circuits: Greenberger–Horne–Zeilinger circuits, phase dependent circuits, and a quantum …

Shadows Of A Schwarzschild Black Hole Surrounded By A Spherically Symmetric Dark Matter, Ahmad Ibrahim

Theses and Dissertations

In this thesis, using general relativity, the null geodesics and black hole shadow of a spherically symmetric configuration of a black hole (surrounded by a dark matter shell) are studied. First, the standard

results of the photon sphere of Schwarzschild de-Sitter black hole is revisited and analyzed more carefully. Secondly, using an ansatz (piecewise metric function) commonly used in the literature to describe the mass distribution of the spherically symmetric black hole - dark matter configuration, the null geodesics through vacuum and dark matter are analyzed. Assuming an observer located at a finite distance from the black hole outside the …

Development Of Novel Intracavitary Intensity Modulated Brachytherapy Applicators For Optimizing The Target Coverage In Gynecologic Malignancies, Monte Carlo Simulation Dosimetry, Moeen Meftahi

Theses and Dissertations

Gynecologic brachytherapy (GYN-BT) is essential for treating cervical and endometrial cancers, the most prevalent female reproductive cancers. This technique enables high radiation doses to a target with rapid dose fall-off to protect adjacent healthy organs. This dissertation aims to address some of the limitations of intracavitary GYN-BT using an intensity modulated brachytherapy (IMBT) technique and Monte Carlo (MC) simulations.

First, a novel non-invasive shielded vaginal cylinder (VC) applicator was designed to provide optimized radiation coverage for the target volume at vaginal apex, site of most recurrences without BT, for endometrial cancer BT. Physical limitations of current applicators and their resulting …

Multi-Modality Automatic Lung Tumor Segmentation Method Using Deep Learning And Radiomics, Siqiu Wang

Theses and Dissertations

Delineation of the tumor volume is the initial and fundamental step in the radiotherapy planning process. The current clinical practice of manual delineation is time-consuming and suffers from observer variability. This work seeks to develop an effective automatic framework to produce clinically usable lung tumor segmentations. First, to facilitate the development and validation of our methodology, an expansive database of planning CTs, diagnostic PETs, and manual tumor segmentations was curated, and an image registration and preprocessing pipeline was established. Then a deep learning neural network was constructed and optimized to utilize dual-modality PET and CT images for lung tumor segmentation. …

Engineered Nanostructured Nitrogen-Doped Carbon Network (Ndc) Electrodes With Unprecedented Cycling Stability For Water Capacitive Deionization In Harsh Conditions, Soha Essam Anwar

Theses and Dissertations

Capacitive deionization (CDI) is a feasible low-cost desalination technique for low-to-medium (brackish) salinity water. However, cycling stability and regeneration of the CDI electrodes are the bottlenecks hindering the practical application of the technology on large scale. Oxidation of the electrodes during the sequential adsorption-desorption processes is one of the most challenging problems hindering their long-term cycling performance. Herein, we demonstrated the ability to design and fabricate exceptionally stable CDI electrodes via a one-pot pyrolysis protocol. The optimized pyrolysis of nitrogen-carbon precursors at different temperatures enabled the fabrication of carbon materials with a controlled amount nitrogen dopant (NDCs) with exceptional cycling …

The Design Of A New Vaginal Applicator For Direction Modulated Brachytherapy (Dmbt) Using Geant4 Monte Carlo Simulation Code, Moeen Meftahi

Theses and Dissertations

Purpose: Anisotropy of the 192Ir source causes a lack of dose coverage at the apex in HDR vaginal cylinder brachytherapy (VC BT). In this study, we took advantage of the GEANT4 Monte Carlo (MC) simulation code to design a new DMBT vaginal applicator so that it maintains the dose coverage of the current vaginal cylinder at periphery everywhere while improving the apex coverage. In addition, since current treatment planning systems (TPS) considers the whole environment as water according to TG43 formalism, based on the capability of the MC in the calculation of dose in the material, the effect of inhomogeneity …

Searching For Clean Observables In $B -> D* /Tau- \Bar{\Nu}_{\Tau}$ Decays, Michael D. Williams Jr.

Theses and Dissertations

In this thesis, the clean angular observables in the $\bar{B} \to D^{*+} \ell^- \bar{\nu}_{\ell}$ angular distribution is studied. Similar angular observables are widely studied in $B \to K^* \mu^+ \mu^-$ decays. We believed that these angular observables may have different sensitivities to different new physics structures.

Theoretical Studies Of The Structure And Stability Of Metal Chalcogenide Crntem (1≤N≤6, 1≤M≤8) Clusters, Fnu Sweta Prabha

Theses and Dissertations

In the presented work, first principle studies on electronic structure, stability, and magnetic properties of metal chalcogenide, Cr_nTe_m clusters have been carried out within a density functional framework using generalized gradient functions to incorporate the exchange and correlation effects. The energetic and electronic stability was investigated, and it was found that they are not always correlated as seen in the cluster Cr₆Te₈ which has smaller gap between its HOMO (Highest Occupied Molecular Orbital) and LUMO (Lowest Unoccupied Molecular Orbital) and a high electron affinity of 3.39 eV indicating lower electronic stability whereas higher fragmentation …

Impacts Of Sub-Auroral Polarization Streams On High Frequency Operations As A Function Of Modeled Particle Energy Flux, Nathan D. Smith

Theses and Dissertations

Space weather events can cause irregularities within the ionosphere; in particular, this research examines sub-auroral polarization streams (SAPS), as their accompanying irregularities and effects can degrade high-frequency (HF) signal propagation. It is known that the strongest westerly current drifts delineating SAPS are associated with a deep ionospheric trough, which in turn contaminates HF data with clutter from the non-standard ionosphere. Having a methodology to track and identify these occurrences on current computational architecture would provide operators enhanced situational awareness in knowing to expect degradation in HF processes. This study has discovered a weak, yet significant, exponentially decaying correlation between maximum …

Improving Fallout Characterization By Using Multivariate Techniques To Determine Composition, Christopher R. Pitkins

Theses and Dissertations

Multivariate statistical techniques have been applied in order to un-mix nuclear fallout debris chemical data. This information is critical to characterization of fallout particle formation following a nuclear detonation. Understanding the correlation between environmental precursors and actinide concentrations in post-detonation nuclear fallout material aids in understanding the physical and chemical processes that alter nuclear device signatures in the fireball. This research examines 123 nuclear fallout samples from a historical nuclear test. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) are used to collect chemical compositions of the fallout samples. Principal component analysis (PCA) is applied in order to examine …

Warp Drive Spacetimes, Nicholas A.S. Driver

Theses and Dissertations

The concept of faster than light travel in general relativity is examined, starting with a review of the Alcubierre metric. This spacetime, although incredible in its implications, has certain unavoidable problems which are discussed in detail. It is demonstrated that in order to describe faster than light travel without any ambiguities, a coordinate independent description is much more convenient. An alternative method of describing superluminal travel is then proposed, which has similarities to the Krasnikov tube.

Geodesic Structure In Schwarzschild Geometry With Extensions In Higher Dimensional Spacetimes, Ian M. Newsome

Theses and Dissertations

From Birkoff's theorem, the geometry in four spacetime dimensions outside a spherically symmetric and static, gravitating source must be given by the Schwarzschild metric. This metric therefore satisfies the Einstein vacuum equations. If the mass which gives rise to the Schwarzschild spacetime geometry is concentrated within a radius of r=2M, a black hole will form. Non-accelerating particles (freely falling) traveling through this geometry will do so along parametrized curves called geodesics, which are curved space generalizations of straight paths. These geodesics can be found by solving the geodesic equation. In this thesis, the geodesic structure in the Schwarzschild geometry …

Motion-Induced Artifact Mitigation And Image Enhancement Strategies For Four-Dimensional Fan-Beam And Cone-Beam Computed Tomography, Matthew J. Riblett

Theses and Dissertations

Four dimensional imaging has become part of the standard of care for diagnosing and treating non-small cell lung cancer. In radiotherapy applications 4D fan-beam computed tomography (4D-CT) and 4D cone-beam computed tomography (4D-CBCT) are two advanced imaging modalities that afford clinical practitioners knowledge of the underlying kinematics and structural dynamics of diseased tissues and provide insight into the effects of regular organ motion and the nature of tissue deformation over time. While these imaging techniques can facilitate the use of more targeted radiotherapies, issues surrounding image quality and accuracy currently limit the utility of these images clinically.

The purpose of …

Kinetic Monte Carlo Simulation Of Binary Alloys, Timothy Craig Marshall

Theses and Dissertations

There are many tools to simulate physical phenomena. Generally, the simulation technique is defined by the size of the simulation area. Two well know techniques for simulating atom dynamics are kinetic Monte Carlo (kMC) and molecular dynamics (MD). In this work we simulate physical vapor deposition of binary metallic systems using the kMC technique. A sufficient quantity of atoms are deposited so that morphological features can be observed. Where kMC has fallen short we have used MD to supplement our results.

Gravitational Microlensing, Wesley M. Barnes

Theses and Dissertations

A gravitational microlensing event occurs when a foreground star passes near our line of site to a background source star. The foreground star acts as a lens, perturbing the image of the source star and amplifying the apparent intensity. Because the lens is in motion relative to the source star, the amplification is a function in time, resulting in a characteristic microlensing light curve. If the lens happens to have a planetary companion, the resulting light curve will be perturbed due the planet and the characteristics of the binary system can be ascertained.

Application Of The Fisher Dimer Model To Dna Condensation, John C. Baker Iii

Theses and Dissertations

This paper considers the statistical mechanics occupation of the edge of a single helix of DNA by simple polymers. Using Fisher's exact closed form solution for dimers on a two-dimensional lattice, a one-dimensional lattice is created mathematically that is occupied by dimers, monomers, and holes. The free energy, entropy, average occupation, and total charge on the lattice are found through the usual statistical methods. The results demonstrate the charge inversion required for a DNA helix to undergo DNA condensation.

Understanding And Design Of An Arduino-Based Pid Controller, Dinesh Bista

Theses and Dissertations

This thesis presents research and design of a Proportional, Integral, and Derivative (PID) controller that uses a microcontroller (Arduino) platform. The research part discusses the structure of a PID algorithm with some motivating work already performed with the Arduino-based PID controller from various fields. An inexpensive Arduino-based PID controller designed in the laboratory to control the temperature, consists of hardware parts: Arduino UNO, thermoelectric cooler, and electronic components while the software portion includes C/C++ programming. The PID parameters for a particular controller are found manually. The role of different PID parameters is discussed with the subsequent comparison between different modes …

Self-Force On Accelerated Particles, Thomas Michael Linz

Theses and Dissertations

The likelihood that gravitational waves from stellar-size black holes spiraling into a supermassive black hole would be detectable by a space based gravitational wave observatory has spurred the interest in studying the extreme mass-ratio inspiral (EMRI) problem and black hole perturbation theory (BHP). In this approach, the smaller black hole is treated as a point particle and its trajectory deviates from a geodesic due to the interaction with its own field. This interaction is known as the gravitational self-force, and it includes both a damping force, commonly known as radiation reaction, as well as a conservative force. The computation of …

Λcdm Cosmology + Chaotic Inflation, Peter A. Farago

Theses and Dissertations

ΛCDM cosmology is described in terms of general relativity and the Robertson-Walker metric. The evolution of the observable universe, currently dominated by dark energy (Λ) and cold dark matter (CDM), is presented in terms of its thermal history. CDM is extended to include an inflation epoch that accelerates the early expansion rate to near exponential levels. It is shown that inflation solves several problems in CDM and produces perturbations in the metric that lead to the observed anisotropies in the Cosmic Microwave Background and the formation of large scale cosmological structures. Various theories of inflation are explored. Predictions of inflation …

An Investigation Of Nurbs-Based Deformable Image Registration, Travis J. Jacobson

Theses and Dissertations

Deformable image registration (DIR) is an essential tool in medical image processing. It provides a means to combine image datasets, allowing for intra-subject, inter-subject, multi-modality, and multi-instance analysis, as well as motion detection and compensation. One of the most popular DIR algorithms models the displacement vector field (DVF) as B-splines, a sum of piecewise polynomials with coefficients that enable local shape control. B-splines have many advantageous properties in the context of DIR, but they often struggle to adequately model steep local gradients and discontinuities. This dissertation addresses that limitation by proposing the replacement of conventional B-splines with a generalized formulation …

Beyond The Standard Model: Lhc Phenomenology, Cosmology From Post-Inflationary Sources, And Dark Matter Physics, Brian J. Vlcek

Theses and Dissertations

It is the goal of this dissertation to demonstrate that beyond the standard model, certain theories exist which solve conflicts between observation and theory -- conflicts such as massive neutrinos, dark matter, unstable Higgs vacuum, and recent Planck observations of excess relativistic degrees of freedom in the early universe. Theories explored include a D-brane inspired construct of U(3) × Sp(1) × U(1) × U(1) extension of the standard model, in which we demonstrate several possible observables that may be detected at the LHC, and an ability to stabilize the Higgs mechanism. The extended model can also explain recent Planck data …

Multimessenger Approach To Search For Cosmic Ray Anisotropies, Larry David Buroker

Theses and Dissertations

The origin of the highest energy cosmic rays is still unknown. The discovery of their sources will reveal the workings of the most energetic astrophysical accelerators in the universe. Recent international efforts have brought us closer to unveiling this mystery. Possible ultra-high energy cosmic ray sources have been narrowed down with the confirmation of an "ankle" and the GZKlike spectral feature at the high-end of the energy spectrum. A clear resolution of the ultra-high energy mystery calls for the search of anisotropies in the distribution of arrival directions of cosmic rays. In this thesis, we adopt the so-called "multi-messenger" approach …

Hyperspectral Imaging Of A Turbine Engine Exhaust Plume To Determine Radiance, Temperature, And Concentration Spatial Distributions, Spencer J. Bowen

Theses and Dissertations

The usefulness of imaging Fourier transform spectroscopy (IFTS) when looking at a rapidly varying turbine engine exhaust scene was explored by characterizing the scene change artifacts (SCAs) present in the plume and the effect they have on the calibrated spectra using the Telops, Inc.-manufactured Field-portable Imaging Radiometric Spectrometer Technology, Midwave Extended (FIRST-MWE). It was determined that IFTS technology can be applied to the problem of a rapidly varying turbine engine exhaust plume due to the zero mean, stochastic nature of the SCAs, through the use of temporal averaging. The FIRST-MWE produced radiometrically calibrated hyperspectral datacubes, with calibration uncertainty of 35% …

Testing Of The New Usgs K Index Algorithm At Bear Lake Observatory, Ariel O. Acebal

Theses and Dissertations

The K index was developed by Bartels in 1939 as an estimate of the level of geomagnetic activity caused by the Sun. This index was computed manually every three hours at geomagnetic observatories using the magnetic traces of the surface planetary magnetic field. In 1991, the International Association of Geomagnetism and Aeronomy approved four additional methods to compute the K index; all of them were computer algorithms. One of the approved methods, the Wilson code, recently underwent some modifications. The new algorithm is now part of a Windows-based computer program being developed by the United States Geological Survey (USGS). After …

Displacement Of The Earth's Bow Shock And Magnetopause Due To An Impinging Interplanetary Shock Wave, William A. Olson

Theses and Dissertations

Interplanetary shock waves (ISWs) propagating through the solar wind can collide with the earth's bow shock, resulting in a series of new shocks, contact discontinuities, and rarefaction waves which interact to effectively move the bow shock and magnetopause toward the earth. A one dimensional MacCormack predictor corrector algorithm with Flux Corrected Transport (FCT) was developed to model the ISW bow shock and magnetopause interactions, and to numerically predict their propagation speeds after collision. Analytic relationships for the Mach numbers and propagation speeds of the generated shock waves and contact discontinuities were used to validate the model and to compare numerical …