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Synthesis Of Al2tio5 And Its Effect On The Properties Of Chitosan-Nh4scn Polymer Electrolytes, Siti Rohana Majid, Hassan F., Woo H. J., Aziz N. A., Kufian M. Z. Dec 2012

Synthesis Of Al2tio5 And Its Effect On The Properties Of Chitosan-Nh4scn Polymer Electrolytes, Siti Rohana Majid, Hassan F., Woo H. J., Aziz N. A., Kufian M. Z.

Siti Rohana Majid

In this paper, Al2TiO5 ceramic material has been synthesised and used as filler in polymer electrolyte system to enhance the conductivity. The precursor sintered at 1,050 A degrees C and contained 0.08 mole of aluminium nitrate gives the best and complete formation of Al2TiO5. Composite polymer electrolytes of chitosan-NH4SCN containing different amount of home-made Al2TiO5 were prepared by solution casting. The addition of filler has enhanced the conductivity of polymer electrolyte. The sample 57 wt% chitosan-38 wt% NH4SCN-5 wt% Al2TiO5 exhibited the highest electrical conductivity of 2.10 x 10(-4) S cm(-1) at room temperature. The presence of the Al2TiO5 creates …


The Effect Of Antimony Trioxide On Poly (Vinyl Alcohol)-Lithium Perchlorate Based Polymer Electrolytes, Siti Rohana Majid, Lim C. S., Ramesh S. Dec 2012

The Effect Of Antimony Trioxide On Poly (Vinyl Alcohol)-Lithium Perchlorate Based Polymer Electrolytes, Siti Rohana Majid, Lim C. S., Ramesh S.

Siti Rohana Majid

A new type of inorganic filler antimony trioxide (Sb2O3) is used to prepare composite polymer electrolytes based on poly (vinyl alcohol) (PVA) and lithium perchlorate (LiClO4) by solution casting technique. The incorporation of Sb2O3 enhances the ionic conductivity at ambient temperature and exhibits the highest ionic conductivity value of 9.51 x 10(-5) S cm(-1) upon the addition of 6 wt% Sb2O3. Thermogravimetric analyses (TGA) reveal that the second weight loss is reduced. This shows the improvement in thermal stability of electrolyte film upon addition of Sb2O3. Differential scanning calorimetry (DSC) analyses show that the glass transition temperature (T-g) value decreases …