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The Effect Of Antimony Trioxide On Poly (Vinyl Alcohol)-Lithium Perchlorate Based Polymer Electrolytes, Siti Rohana Majid, Lim C. S., Ramesh S.
The Effect Of Antimony Trioxide On Poly (Vinyl Alcohol)-Lithium Perchlorate Based Polymer Electrolytes, Siti Rohana Majid, Lim C. S., Ramesh S.
Siti Rohana Majid
A new type of inorganic filler antimony trioxide (Sb2O3) is used to prepare composite polymer electrolytes based on poly (vinyl alcohol) (PVA) and lithium perchlorate (LiClO4) by solution casting technique. The incorporation of Sb2O3 enhances the ionic conductivity at ambient temperature and exhibits the highest ionic conductivity value of 9.51 x 10(-5) S cm(-1) upon the addition of 6 wt% Sb2O3. Thermogravimetric analyses (TGA) reveal that the second weight loss is reduced. This shows the improvement in thermal stability of electrolyte film upon addition of Sb2O3. Differential scanning calorimetry (DSC) analyses show that the glass transition temperature (T-g) value decreases …
Transport Studies Of Nh4no3 Doped Methyl Cellulose Electrolyte, Siti Rohana Majid, Shuhaimi N. E. A., Teo L. P., Arof A. K.
Transport Studies Of Nh4no3 Doped Methyl Cellulose Electrolyte, Siti Rohana Majid, Shuhaimi N. E. A., Teo L. P., Arof A. K.
Siti Rohana Majid
This work reports on the transport properties of NH4NO3 doped methyl cellulose (MC) polymer electrolyte. The polymer electrolyte films were prepared by the technique of solvent casting. The highest room temperature conductivity of MC doped with 25 wt.% NH4NO3 is 2.10 +/- 0.37 x 10(-6) S cm(-1). Conductivity-temperature relationship obeys the Vogel-Tamman-Fulcher (VTF) rule from which the glass transition temperature, T-g was evaluated. The mobility, p and number density of charge carrier, n were calculated using the Rice and Roth model. (C) 2010 Elsevier B.V. All rights reserved.