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Full-Text Articles in Physics

Predicting The Hydrogen Pressure To Achieve Ultralow Friction And Diamondlike Carbon Surfaces From First Principles, Haibo Guo, Yue Qi, Xiaodong Li Jun 2008

Predicting The Hydrogen Pressure To Achieve Ultralow Friction And Diamondlike Carbon Surfaces From First Principles, Haibo Guo, Yue Qi, Xiaodong Li

Faculty Publications

Hydrogen atmosphere can significantly change the tribological behavior at diamond and diamondlike carbon (DLC) surfaces and the friction-reducing effect depends on the partial pressure of hydrogen. We combined density functional theory modeling and thermodynamic quantities to predict the equilibrium partial pressures of hydrogen at temperature T, PH2 (T), for a fully atomic hydrogen passivated diamondsurface. Above the equilibrium PH2 (T), ultralow friction can be achieved at diamond and DLC surfaces. The calculation agrees well with friction tests at various testing conditions. We also show that PH2 (T) …


Self-Assembled Composite Nano-/Micronecklaces With Sio2 Beads In Boron Strings, Hai Ni, Xiaodong Li Jul 2006

Self-Assembled Composite Nano-/Micronecklaces With Sio2 Beads In Boron Strings, Hai Ni, Xiaodong Li

Faculty Publications

Nano-/micronecklaces with SiO2 beads in boron strings were synthesized by simply sublimating the desired powders in a sealed quartz tube at high temperature. The boron strings have a rectangular cross section with width varying from 80to1000nm while the SiO2 beads bear either spindle or spherical shape with a size ranging from 100nmto5μm. The spacing between the SiO2 beads is uniform in each boron string. Both the boron strings and the SiO2 beads are amorphous and free of defects. The supersaturated vapors of silicon and oxygen induced the SiO2 bead formation.