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Viscous Liquids And The Glass Transition At Extremely High Pressure: Optical Techniques Applied To Cumene In A Diamond Anvil Cell, Timothy Craig Ransom

Graduate Theses and Dissertations

This dissertation presents the results from experiments studying the pressure-dependence of properties associated with the glass transition in the glass-forming liquid cumene. Through the use of a diamond anvil cell, we achieve extremely high pressures over 40,000 atmospheres. A new technique is refined to directly measure the glass transition temperature Tg extremely accurately, and we show that thermodynamic scaling is capable of describing the liquid�glass transition boundary up to record-high pressures. Optical techniques are also implemented to probe the system dynamics in the viscous regime leading up to the glass transition. We present laser light-scattering measurements of the dynamic susceptibility …