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Optics

Theses and Dissertations

2022

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Full-Text Articles in Physics

Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen Dec 2022

Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen

Theses and Dissertations

The widespread pollution of mercury motivates research into its atmospheric chemistry and transport. Gaseous elemental mercury (Hg(0)) dominates mercury emission to the atmosphere, but the rate of its oxidation to mercury compound (Hg(II)) plays a significant role in controlling where and when mercury deposits to ecosystems. Atomic bromine is regarded as the main oxidant for Hg(0) oxidation, known to initiate the oxidation via a two-step process in the atmosphere – formation of BrHg (R1) and subsequent reactions of BrHg with abundant free radicals Y, i.e., NO2, HOO, etc. (R2), where the reaction of BrHg +Y could also lead to the …

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Fitting Solar Panel Brdf Parameters To Out-Of-Plane Empirical Data, Michael R. Gross Dec 2022

Fitting Solar Panel Brdf Parameters To Out-Of-Plane Empirical Data, Michael R. Gross

Theses and Dissertations

The bidirectional reflectance distribution function (BRDF) describes material reflectance by describing how incident irradiance reflects into all possible scatter angles as a function of incident angle. However, a solar panel has unique features that are not featured in any of these previously known models. A previous project at the Air Force Institute of Technology (AFIT) created a novel microfacet-like BRDF to model a solar panel with a prominent diffractive feature present which had not been previously modeled. This BRDF was coded into MATLAB for modeling purposes and C++ to test its speed with a MEX function call. A previous thesis …

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Optimizing Optical Switching Of Non-Linear Optimizing Optical Switching Of Non-Linear Hyperbolic Metamaterials, James A. Ethridge Sep 2022

Optimizing Optical Switching Of Non-Linear Optimizing Optical Switching Of Non-Linear Hyperbolic Metamaterials, James A. Ethridge

Theses and Dissertations

Modern optical materials are engineered to be used as optical devices in specific applications, such as optical computing. For optical computing, efficient forms of a particular device, the optical switch, still have not been successfully demonstrated. This problem is addressed in this research through the use of designed optical metamaterials, specifically, hyperbolic metamaterials, which offer the possibility of large non-linear properties with a low switching intensity. One-dimensional layered hyperbolic metamaterials composed of alternating layers of metal and dielectric were used here, with ITO as the metal and SiO2 as the dielectric. The non-linear behavior of the ITO/SiO2 layered …

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Methods For Focal Plane Array Resolution Estimation Using Random Laser Speckle In Non-Paraxial Geometries, Phillip J. Plummer Jun 2022

Methods For Focal Plane Array Resolution Estimation Using Random Laser Speckle In Non-Paraxial Geometries, Phillip J. Plummer

Theses and Dissertations

The infrared (IR) imaging community has a need for direct IR detector evaluation due to the continued demand for small pixel pitch detectors, the emergence of strained-layer-super-lattice devices, and the associated lateral carrier diffusion issues. Conventional laser speckle-based modulation transfer function (MTF) estimation is dependent on Fresnel propagation and a wide-sense-stationary input random process, limiting the use of this approach for lambda (wavelength)-scale IR devices. This dissertation develops two alternative methodologies for speckle-based resolution evaluation of IR focal plane arrays (FPAs). Both techniques are formulated using Rayleigh-Sommerfield electric field propagation, making them valid in the non-paraxial geometries dictated for resolution …

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Formulation And Characterization Of Fast-Curing Plastic Scintillators With High-Z Loading, Theodore W. Stephens Mar 2022

Formulation And Characterization Of Fast-Curing Plastic Scintillators With High-Z Loading, Theodore W. Stephens

Theses and Dissertations

Development of novel fast-curing plastic scintillators is highly advantageous due to their potential to be manufactured via 3D printing. Several formulations were developed that exhibit enhanced photon sensitivity, producing modest but discernible photopeaks at an incident gamma energy of 122 keV. The photon sensitivity is achieved via bismuth high-Z loading; however, this practice typically results in diminished light yields. Subsequent formulations, which varied the photoinitiator concentration and curing time, demonstrated successful curing with sufficient plastic hardness, reduced purple discoloration, reduced heat buildup during curing, and resulted in less cracking during the curing process, all of which were correlated with lower …

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Directionally Sensitive Gamma Imaging Using Rotating Scatter Masks And Inexpensive, Scintillation Detectors, Christopher S. Charles Mar 2022

Directionally Sensitive Gamma Imaging Using Rotating Scatter Masks And Inexpensive, Scintillation Detectors, Christopher S. Charles

Theses and Dissertations

This work demonstrates the first instantiation of the FitzGerald Rotating Scatter Mask (RSM) as a proof-of-concept for two-dimensional source direction determination using a single, inexpensive, non-cooled scintillator, as well as an alternate mask design for comparison. A large RSM was additively manufactured from low-Z, acrylic like material, and rotated around the ubiquitous standard 3" x 3" NaI(Tl) or NaI(Tl)/CsI(Tl) phoswich detector, set internally to the mask. Smaller versions of the FitzGerald and alternate RSM designs were 3D printed for testing and used in conjunction with a LaBr detector to characterize the RSM system with a size and weight reduction applied. …

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