Physics Commons^™

Interlaboratory Comparison Of Δ13c And Δd Measurements Of Atmospheric Ch4 For Combined Use Of Data Sets From Different Laboratories, Taku Umezawa, Carl Brenninkmeijer, Thomas Röckmann, Carina Van Der Veen, Stanley C. Tyler, Ryo Fujita, Shinji Morimoto, Shuji Aoki, Todd Sowers, Jochen Schmitt, Michael Bock, Jonas Beck, Hubertus Fischer, Sylvia E. Michel, Bruce H. Vaughn, John B. Miller, James W.C. White, Gordon Brailsford, Hinrich Schaefer, Peter Sperlich, Willi A. Brand, Michael Rothe, Thomas Blunier, David Lowry, Rebecca E. Fisher, Euan G. Nisbet, Andrew L. Rice, Peter Bergamaschi, Cordelia Veidt, Ingeborg Levin

Physics Faculty Publications and Presentations

We report results from a worldwide interlaboratory comparison of samples among laboratories that measure (or measured) stable carbon and hydrogen isotope ratios of atmospheric CH₄ (δ¹³C-CH₄ and δD-CH₄). The offsets among the laboratories are larger than the measurement reproducibility of individual laboratories. To disentangle plausible measurement offsets, we evaluated and critically assessed a large number of intercomparison results, some of which have been documented previously in the literature. The results indicate significant offsets of δ¹³C-CH₄ and δD- CH₄ measurements among data sets reported from different laboratories; the differences among laboratories …