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Full-Text Articles in Physics

Heterogeneous Rotational Diffusion Of A Fluorescent Probe In Lipid Monolayers, Christina M. Othon Aug 2014

Heterogeneous Rotational Diffusion Of A Fluorescent Probe In Lipid Monolayers, Christina M. Othon

Christina M Othon

The rotational correlation time of the lipid probe 1-palmitoyl-2-{6-[(7-nitro-2-1,3-benzoxadiazol-4-yl)amino]hexanoyl}-sn-glycero-3-phosphocholine (NBD-PC) is measured using fluorescence anisotropy for two lipid species. We measure the rotational diffusion in a monolayer of 1,2-Didecanoyl-sn-glycero-3-phosphocholine (DPPC) which displays a phase transition at room temperature from the liquid expanded to the liquid-condensed phase. The constant rotational diffusion of the probe throughout the phase transition reflects the measurement of dynamics in only the liquid-expanded phase. We contrast the dynamic changes during this phase coexistence to the continuous density increase observed in 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) at room temperature. We observe a non-exponential decay of the probe diffusion consistent with heterogeneity …


Pubspectra To Do Data, George Mcnamara May 2014

Pubspectra To Do Data, George Mcnamara

George McNamara

PubSpectra raw data that I had in my "to do" folder to add to the PubSpectra data set but never did.

PubSpectra has over 2000 spectra in it (last updated 2006) in Excel "big file" format - the XLSX file inside the zip file at

http://works.bepress.com/gmcnamara/9/

Anyone is welcome to add and organize new data yourselves. I used Un-Scan-It from Silk Scientific (www.silkscientific.com).

More importantly, I strongly adopting my PubSpectra format of 1 nm wavelength intervals, with the row number corresponding to nm. For example, 400 nm data appears in row 400.

Much of Urse Utzinger's "Spectra Arizona" data,

http://www.spectra.arizona.edu/ …


Inducing A Dielectric Barrier Discharge Plasma Within A Package, Vladimir Milosavljevic Jan 2014

Inducing A Dielectric Barrier Discharge Plasma Within A Package, Vladimir Milosavljevic

Vladimir Milosavljevic

Cold atmospheric plasma offers significant potential as a nonthermal decontamination tool for food and medical applications. We present results of a dielectric barrier discharge (DBD) plasma induced in a gas confined by a polymer package. The resultant discharge and contained afterglow are found to have a strong antimicrobial effect.


Inducing A Dielectric Barrier Discharge Plasma Within A Package, Vladimir Milosavljevic Jan 2014

Inducing A Dielectric Barrier Discharge Plasma Within A Package, Vladimir Milosavljevic

Vladimir Milosavljevic

Cold atmospheric plasma offers significant potential as a nonthermal decontamination tool for food and medical applications. We present results of a dielectric barrier discharge (DBD) plasma induced in a gas confined by a polymer package. The resultant discharge and contained afterglow are found to have a strong antimicrobial effect.


Enzyme Entrapment In Polyaniline Films Observed Via Florescence Anisotropy And Antiquenching, Louis R. Nemzer, Marissa Mccaffrey, Arthur J. Epstein Jan 2014

Enzyme Entrapment In Polyaniline Films Observed Via Florescence Anisotropy And Antiquenching, Louis R. Nemzer, Marissa Mccaffrey, Arthur J. Epstein

Louis R Nemzer

The facile entrapment of oxidoreductase enzymes within polyaniline polymer films by inducing hydrophobic collapse using phosphate buffered saline (PBS) has been shown to be a cost-effective method for fabricating organic biosensors. Here, we use fluorescence anisotropy measurements to verify enzyme immobilization and subsequent electron donation to the polymer matrix, both prerequisites for an effective biosensor. Specifically, we measure a three order of magnitude decrease in the ratio of the fluorescence to rotational lifetimes. In addition, the observed fluorescence antiquenching supports the previously proposed model that the polymer chain assumes a severely coiled conformation when exposed to PBS. These results help …