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Full-Text Articles in Physics
Scene Change Artifacts In Fourier Transform Spectroscopy Of Temporally Changing Sources, Anthony M. Young
Scene Change Artifacts In Fourier Transform Spectroscopy Of Temporally Changing Sources, Anthony M. Young
Theses and Dissertations
Improved understanding of midwave infrared (1-5 micron) spectral emissions from detonation fireballs is needed to develop phenomenological models for battle space optical forensics. The ability to measure radiance over a wide band pass at arbitrary resolutions make Fourier-transform spectrometers (FTS) an attractive tool. However, interferometer based spectroscopic measurements can be corrupted when the observed intensity changes during data acquisition. While small, random fluctuations in scene intensity translate into noise, systematic variations introduce scene-change artifacts (SCAs) into Fourier-transformed spectrum.
Analysis Of Expedient Field Decontamination Methods For The Xmx/2l-Mil High-Volume Aerosol Sampler, Brandon C. Laroche
Analysis Of Expedient Field Decontamination Methods For The Xmx/2l-Mil High-Volume Aerosol Sampler, Brandon C. Laroche
Theses and Dissertations
The XMX/2L-MIL is a high volume air sampler used by the Air Force Bioenvironmental Engineering community to collect biological aerosols. Without a verified decontamination technique, however, the XMX cannot be used effectively. The objective of this study was to evaluate several proposed methods for expedient field decontamination of the XMX. This study centered on the inactivation of Bacillus atrophaeus spores and vegetative Erwinia herbicola organisms from the XMX inner canister. The goals in this investigation were twofold: 1) to verify the antimicrobial efficacy of a 10% bleach solution and 2) to determine if wiping the components with a bleach-soaked paper …
Laser-Induced Breakdown Spectroscopy On Solution Samples Using Surface Excitation, Leonard M. Berman
Laser-Induced Breakdown Spectroscopy On Solution Samples Using Surface Excitation, Leonard M. Berman
Theses and Dissertations
Laser-induced breakdown spectroscopy (LIBS) is a spectroscopic technique where output from a pulsed laser is focused onto a target in order to create an intense plasma. The optical emission is characteristic of the elements in the focal volume and can be used for elemental analysis. Research on the detection of nickel in solution in addition to solvent detection of CCl4, CHCl3, C2Cl4, and C2HCl3 has been performed. Breakdown was formed at the sample surface via a Q-switched Nd:YAG laser. Initially, operation of the laser was at 1064 nm/repetition rate of 5 Hz. Experiments …
Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt
Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt
Theses and Dissertations
This research investigated the influence of soil characteristics on the desorption of trichloroethylene (TCE). TCE is one of the most common contaminants at Superfund sites. Unfortunately, extraction of TCE from contaminated soils has been hindered by its slow and poorly understood desorption from soil particles. The rate and progress of desorption of TCE from seven types of soil with varying particle diameters and elemental compositions was measured using optical absorption techniques. Fitting the data to the Langmuir Isotherm functional form predicted in the literature yielded parameters for the desorption rate and total amount desorption each soil type. These parameters were …
Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares
Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares
Theses and Dissertations
This thesis investigated the influence of temperature on the desorption rated of trichloroethylene (TCE) from plastic clay. It was expected that an increase in temperature will cause an increase in both the desorption rates of TCE and in the desorbed quantity. Previous studies on other chemicals indicated a faster decrease in the remaining sorbed concentration with an increase in temperature. This research made use of the infrared optical absorption technique. IR spectroscopy was used to measure the concentration of the vapor TCE that desorbed from the soil. The soil was exposed to liquid TCE for 2 days then placed inside …