Physics Commons^™

Strain-Enhanced Coherent Exciton-Polaron States In 1d Phthalocyanine Crystalline Thin Films, Libin Liang

Graduate College Dissertations and Theses

Organic semiconductors are at the forefront of materials research, due to their desired electric and mechanical properties. They offer the unique opportunity to modify material properties during synthesis process, opening an avenue to the development of novel flexible and wearable electronic and photonic devices.Molecular excitons are of importance in organic semiconductor properties. While majority of research studies are centered on achieving good control of amorphous or polycrystalline thin film properties, the static disorder effect leads to poor device performance when compared to inorganic semiconductors with superior crystalline ordering. On the other hand, the macroscopic molecular long-range ordering can enhance device …

Exciton Coherence In 1d Phthalocyanine Based Organic Crystalline Thin Films, Kimngan Burrill

Graduate College Dissertations and Theses

Quantum coherence plays a vital role in the excitonic properties of organic semiconductors. Several theoretical and experimental studies have shown an unprecedented role of coherence in charge transfer and transport processes, which in turn can improve the performance of electronic devices. Specifically, an enhancement of exciton coherence size can result in fast energy transport and efficient charge separation. The ability to tailor the design and performance of organic electronics based on exciton coherence effects represents the possibility of ultrafast electronic applications in communication and information technology.

The objective of this thesis is the excitonic coherence studies of 1D crystalline thin …

Exchange Mechanisms In Macroscopic Ordered Organic Magnetic Semiconductors, Naveen Rawat

Graduate College Dissertations and Theses

Small molecule organic semiconductors such as phthalocyanines and their derivatives represent a very interesting alternative to inorganic semiconductor materials for the development of flexible electronic devices such as organic thin field effect transistors, organic Light Emitting Diodes and photo-voltaic cells. Phthalocyanine molecules can easily accommodate a variety of metal atoms as well in the central core of the molecule, resulting in wide range of magnetic properties. Exploration of optical properties of organic crystalline semiconductors thin films is challenging due to sub-micron grain sizes and the presence of numerous structural defects, disorder and grain boundaries. However, this can be overcome by …