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Neutral Nitrogen Acceptors In Zno: The 67Zn Hyperfine Interactions, Eric M. Golden, S. M. Evans, Larry E. Halliburton, Nancy C. Giles

Faculty Publications

Electron paramagnetic resonance (EPR) is used to characterize the ⁶⁷Zn hyperfine interactions associated with neutral nitrogen acceptors in zinc oxide. Data are obtained from an n-type bulk crystal grown by the seeded chemical vapor transport method. Singly ionized nitrogen acceptors (N⁻) initially present in the crystal are converted to their paramagnetic neutral charge state (N⁰) during exposure at low temperature to 442 or 633 nm laser light. The EPR signals from these N⁰ acceptors are best observed near 5 K. Nitrogen substitutes for oxygen ions and has four nearest-neighbor cations. The zinc ion …