Physics Commons^™

Understanding The Degradation Mechanism In Methyl Ammonium Lead Halide Perovskite And Black Phosphorene Via Electrical Transport Study, Huda Saleh Aljeailan

Theses and Dissertations--Physics and Astronomy

This work seeks to understand the degradation mechanism of technically important material systems such as black phosphorene (BP), arsenic phosphorene (AsP) and Methyl ammonium lead iodide (CH₃NH₃PbI₃) perovskite. Degradation studies were conducted by studying the in-situ electrical transport properties (resistance and thermoelectric power (TEP)) of these materials in vacuum (under annealed condition) and after exposure to the ambient air.

BP and both exhibited p-type semiconducting (positive TEP) behavior under annealed conditions and the changes in their transport properties upon exposure to ambient air can be explained as due to the charge transfer between the …

Tuning Topological Surface States By Charge Transfer, Zhiyi Chen

Dissertations, Theses, and Capstone Projects

Three-dimensional (3D) topological insulators (TIs), Bi₂Se₃, Bi₂Te₃, Sb₂Te₃, are a class of materials that has non-trivial bulk band structure and metallic surface states. Access to charge transport through Dirac surface states in TIs can be challenging due to their intermixing with bulk states or non-topological two-dimensional electron gas quantum well states caused by bending of electronic bands near the surface. The band bending arises via charge transfer from surface adatoms or interfaces and, therefore, the choice of layers abutting topological surfaces is critical. Surfaces of these 3D TIs …