Physics Commons^™

Impact Of Alkaline Doping And Reducing Conditions On Lafeo3, Geoffrey L. Beausoleil Ii

Geoffrey L Beausoleil II

Efficient and reliable materials for gas separation, syngas production, and hybrid nuclear power plants must be capable of reliably operating at a high-temperature range of 700-1000°C and under exposure to highly oxidizing and reducing conditions. Candidate materials for these applications include alkaline metal doped lanthanum ferrite.

In the first study, the impact of A site substitution by different alkaline metals on lanthanum ferrite (LMF, M=Ca, Sr, and Ba) was investigated. The study focused on thermal expansion near the Néel transition temperature and a magneto-elastic contribution to thermal expansion was identified for each sample. Iron oxidation, Fe3+ to Fe4+, was identified …

Structure And Dynamics Of Model Systems: From Ferrofluids To Brain Membranes, Matthew A. Barrett

Matthew J. Barrett

Soft condensed matter systems are a very diverse and challenging subject to study. To understand the complex macro-properties of such systems one approach is to characterize the microscopic structure and dynamics. A powerful technique for determining micro and nanoscale properties is scattering of radiation sources. Light, electron and neutron scattering techniques provide insight into the complicated molecular structures and the processes happening on these small scales. We have used neutron and x-ray scattering techniques to determine structural and dynamical information from two different types of soft condensed matter systems. The microscopic nature of a cobalt magnetic fluid was studied using …

Reflectance Anisotropy Of Gd5si2ge2 And Tb5si2.2ge1.8, S. J. Lee, Joong Mok Park, J. E. Snyder, David C. Jiles, Deborah L. Schlagel, Thomas A. Lograsso, A. O. Pecharsky, David W. Lynch

Professor David Lynch

Reflectance difference (RD) spectra for the a–b plane of the single crystals of Gd5Si2Ge2and b–c planes of Gd5Si2Ge2 and Tb5Si2.2Ge1.8 were obtained in the photon energy range of 1.5–5.5 eV. Several peaks were observed for these crystals in the measured spectrum range. Similar features were observed in the RD spectra for the b–c planes ofGd5Si2Ge2 and Tb5Si2.2Ge1.8, while different features were observed for the a–b plane and b–c plane of Gd5Si2Ge2. The RD spectra for the crystals arise not only from the surface anisotropy but also from the bulk anisotropy due to the monoclinic structure of the bulk crystal.

Effects Of Silver Nanoparticles Towards The Efficiency Of Organic Solar Cells, Khairus Syifa Hamdan, Shahino Mah Abdullah, Khaulah Sulaiman

Shahino Mah Abdullah

We report an alternative approach to enhance the optical and electrical performance of a vanadyl 2,9,16,23-tetraphenoxy-29H,31H-phthalocyanine:poly(3hexylthiophene) (VOPcPhO:P3HT) blending system by integrating plasmonic spherical silver into an active layer of organic solar cells. Studies of the influence of the size distribution and optical properties of the silver nanoparticles were carried out using UV–Vis spectroscopy and field emission scanning electron microscopy, respectively. Electrical characteristics with and without the presence of metallic nanostructures were analyzed using J–V characteristics to observe the plasmonic effects on the performance in the VOPcPhO:P3HT organic solar cells.

On The Transition From Diffusion-Limited To Kinetic-Limited Regimes Of Alloy Solidification, Sergey Sobolev

Sergey Sobolev

An abrupt transition from diffusion-limited solidification to diffusionless, kinetic-limited solidification with complete solute trapping is explained as a critical phenomenon which arises due to local non-equilibrium diffusion effects in the bulk liquid. The transition occurs when the interface velocityVpasses through the critical pointV=VD, where V=VDis the bulk liquid diffusive velocity. Analytical expressions are developed for velocity–temperature and velocity–undercooling functions, using local non-equilibrium partition coeffi-cient based on the Jackson et al. kinetic model and the local non-equilibrium diffusion model of Sobolev. The calculated functions dem-onstrate a sharp break in the velocity–undercooling and velocity–temperature relationships at the critical pointV=VD. At this point …

Novel Nanostructured Rare-Earth-Free Magnetic Materials With High Energy Products, Bhaskar Das

B. Das

Novel nanostructured Zr2Co11-based magnetic materials are fabricated in a single step process using cluster-deposition method. The composition, atomic ordering, and spin structure are precisely controlled to achieve a substantial magnetic remanence and coercivity, as well as the highest energy product for non-rare-earth and Pt-free permanent-magnet alloys.

Bulk Fermi Surface And Momentum Density In Heavily Doped La₂₋ₓsrₓcuo₄ Using High-Resolution Compton Scattering And Positron Annihilation Spectroscopies, W. Al-Sawai, B. Barbiellini, Y. Sakurai, M. Itou, P. E. Mijnarends, R. S. Markiewicz, S. Kaprzyk, S. Wakimoto, M. Fujita, S. Basak, H. Lin, Yung Jui Wang, S. W. H. Eijt, H. Schut, K. Yamada, A. Bansil

Susmita Basak

We have observed the bulk Fermi surface (FS) in an overdoped (x=0.3) single crystal of La₂₋ₓSrₓCuO₄ by using Compton scattering. A two-dimensional (2D) momentum density reconstruction from measured Compton profiles yields a clear FS signature in the third Brillouin zone along [100]. The quantitative agreement between density functional theory (DFT) calculations and momentum density experiment suggests that Fermi-liquid physics is restored in the overdoped regime. In particular the predicted FS topology is found to be in good accord with the corresponding experimental data. We find similar quantitative agreement between the measured 2D angular correlation of positron annihilation radiation (2D-ACAR) spectra …

Electrostatic Discharge Properties Of Fused Silica Coatings, Allen Andersen, Charles Sim, Jr Dennison

Allen Andersen

The electric field value at which electrostatic discharge (ESD) occurs was studied for thin coatings of fused silica (highly disordered SiO2/SiOx) on conductive substrates, such as those encountered as optical coatings and in Si microfabrication. The electrostatic breakdown field was determined using an increasing voltage, while monitoring the leakage current. A simple parallel-plate capacitor geometry was used, under medium vacuum and at temperatures down to ~150 K using a liquid N2 reservoir. The breakdown field, pre-breakdown arcing and I-V curves for fused silica samples are compared for ~60 nm and ~80 μm thick, room and low temperature, and untreated and …

Hfco7-Based Rare-Earth-Free Permanent-Magnet Alloys, Bhaskar Das

B. Das

This study presents the structural and magnetic properties of melt-spun HfCo7,HfCo7-xFex (0.25 ≤ × ≤ 1) and HfCo7Six(0.2 ≤ × ≤1.2) alloys. Appreciable permanent-magnet properties with a magnetocrystalline anisotropy of about 9.6-16.5 Mergs/cm3, a magnetic polarization Js ≈ 7.2-10.6 kG, and coercivities Hc = 0.5-3.0 kOe were obtained by varying the composition of these alloys. Structural analysis reveals that the positions of x-ray diffraction peaks of HfCo7 show good agreement with those corresponding to an orthorhombic structure having lattice parameters of about α = 4.719 Å, b = 4.278 Å, and c = 8.070 Å. Based on these results, a …

Modeling Complex Properties Of Ferroelectric Nanocomposites, Raymond T. Walter

Raymond Walter

No abstract provided.

Bulk Heterojunction Photodiode: To Detect The Whole Visible Spectrum, Shahino Mah Abdullah

Shahino Mah Abdullah

In this paper, we report an organic bulk heterojunction photo-sensor that has been fabricated by using a composite of a polymer material poly(3-hexylthiophene-2,5-diyl) (P3HT) and a dye material vanadyl-phthalocyanine (VOPcPhO). The UV–Vis spectrum shows that this composite exhibits a broad absorption over the whole visible range. The photoluminescence (PL) spectra of P3HT and VOPcPhO blend have been studied to optimize the ratio of P3HT and VOPcPhO. The photo-sensitivity has been investigated under different applied voltages in reverse direction. The photoconductivity sensitivity value has been calculated as 5.65 × 102 Sm/W. The photo-responsivity of the sensor has been investigated under 100 …

Organic Semiconductors: Applications In Solar Photovoltaic And Sensor Devices, Shahino Mah Abdullah

Shahino Mah Abdullah

Organic semiconductor-based solar photovoltaic cells and sensors are scalable, printable, solution processable, bendable and light-weight. Furthermore, organic semiconductors require low energy fabrication process, hence can be fabricated at low cost as light-weight solar cells and sensors, coupled with the ease of processing, as well as compatibility, with flexible substrates. Organic semiconductors have been identified as a fascinating class of novel semiconductors that have the electrical and optical properties of metals and semiconductors. The continuous demand to improve the properties of organic semiconductors raises the quest for a deep understanding of fundamental issues and relevant electronic processes. Organic semiconductor thin film …

Local Nonequilibrium Solute Trapping Model For Non-Planar Interface, Sergey Sobolev

Sergey Sobolev

A generalized solute trapping model was proposed incorporating the dependency on interfacial normal velocity along the dendrite side, as an extension of the continuous growth model modified by Sobolev with the local nonequilibrium diffusion model (LNDM). The present model predicts that the transition to diffusionless solidification is not sharp, but occurs in a range of velocities. Analysis indicates that for local nonequilibrium solute diffusion in bulk liquid the effect of the interfacial normal velocity dependency on solute partitioning is considerable.

Microfabricated Nanotopological Surfaces For Study Of Adhesion-Dependent Cell Mechanosensitivity, Weiqiang Chen, Yubing Sun, Jianping Fu

Weiqiang Chen

Cells exhibit high sensitivity and diverse responses to the intrinsic nanotopography of the extracellular matrix through their nanoscale cellular sensing machinery. A simple microfabrication method for precise control and spatial patterning of the local nanoroughness on glass surfaces by using photolithography and reactive ion etching is reported. It is demonstrated that local nanoroughness as a biophysical cue could regulate a diverse array of NIH/3T3 fi broblast behaviors, including cell morphology, adhesion, proliferation, migration, and cytoskeleton contractility. The capability to control and further predict cellular responses to nanoroughness might suggest novel methods for developing biomaterials mimicking nanotopographic structures in vivo for …

Proton Transfer In Surface-Stabilized Chiral And Polar Motifs Of Croconic Acid, Axel Enders

Axel Enders

No abstract provided.

Vortex-Glass Phase Transition And Enhanced Flux Pinning In C 4+-Irradiated Bafe1.9ni0.1as2 Superconducting Single Crystals, M Shahbazi, X Wang, S Ghorbani, M Ionescu, Olga Shcherbakova, Frederick Wells, Alexey Pan, S Dou, K Choi

Frederick S Wells

We report the effects of C4+-irradiation on the superconducting properties of BaFe1.9Ni0.1As2 single crystal. The BaFe1.9Ni0.1As2 single crystal before and after C4+-irradiation was characterized by magnetic, magneto-transport and magneto-optical techniques over a wide range of magnetic fields (0-13 T) and temperatures (2-200 K). We demonstrate that the C 4+-irradiation significantly enhances the in-field critical current density (by a factor of up to 1.5 at 5 K) and induces enhanced flux jumping at 2 K, with only a small degradation (by 0.5 K) of the critical temperature, T c. The vortex phase diagram describing the evolution of the vortex-glass transition temperature …

Tuning Of Magnetization In Vertical Graphenes By Plasma-Enabled Chemical Conversion Of Organic Precursors With Different Oxygen Content, Zengji Yue

Zengji Yue

Different magnetization in vertical graphenes fabricated by plasma-enabled chemical conversion of organic precursors with various oxygen atom contents and bonding energies was achieved. The graphenes grown from fat-like precursors exhibit magnetization up to 8 emu g−1, whereas the use of sugar-containing precursors results in much lower numbers. A relatively high Curie temperature exceeding 600 K was also demonstrated.

Spin Scattering In Manganese Doped Nickel, Ken Podolak

Dr. Ken Podolak

Spin scattering characteristics of nickel doped with manganese are compared to nickel doped with iron and chromium in nickel. Conclusions are made based on the spin characteristics of the nickel samples doped with manganese with varying percentages in a host nickel crystal. Manganese doping increases the magnetic exchange splitting of nickel, similar to doping with iron and opposite to doping with chromium. On the other hand, manganese doping behaves different from iron with respect the ratio of the majority to minority spin carriers and the ratio of their lifetimes. While iron doping affects both ratios strongly, manganese and chromium doping …