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Full-Text Articles in Physics
Suppression Of Magnetism In Ba5Alir2O11: Interplay Of Hund's Coupling, Molecular Orbitals, And Spin-Orbit Interaction, Sergey V. Streltsov, Gang Cao, Daniel I. Khomskii
Suppression Of Magnetism In Ba5Alir2O11: Interplay Of Hund's Coupling, Molecular Orbitals, And Spin-Orbit Interaction, Sergey V. Streltsov, Gang Cao, Daniel I. Khomskii
Center for Advanced Materials Faculty Publications
The electronic and magnetic properties of Ba5AlIr2O11 containing Ir-Ir dimers are investigated using the generalized gradient approximation (GGA) and GGA + spin-orbit coupling (SOC) calculations. We found that the strong suppression of the magnetic moment in this compound recently found by Terzic et al. [Phys. Rev. B 91, 235147 (2015)] is not due to charge ordering but is related to the joint effect of the spin-orbit interaction and strong covalency, resulting in the formation of metal-metal bonds. They conspire and act against the intraatomic Hund's rule exchange interaction to reduce total magnetic moment of the …
Simultaneous Metal-Insulator And Antiferromagnetic Transitions In Orthorhombic Perovskite Iridate Sr0.94Ir0.78O2.68 Single Crystals, Hao Zheng, Jsaminka Terzic, Feng Ye, X. G. Wan, D. Wang, Jinchen Wang, Xiaoping Wang, P. Schlottmann, Shujuan Yuan, Gang Cao
Simultaneous Metal-Insulator And Antiferromagnetic Transitions In Orthorhombic Perovskite Iridate Sr0.94Ir0.78O2.68 Single Crystals, Hao Zheng, Jsaminka Terzic, Feng Ye, X. G. Wan, D. Wang, Jinchen Wang, Xiaoping Wang, P. Schlottmann, Shujuan Yuan, Gang Cao
Center for Advanced Materials Faculty Publications
The orthorhombic perovskite SrIrO3 is a semimetal, an intriguing exception in iridates where the strong spin-orbit interaction coupled with electron correlations tends to impose an insulating state. We report results of our investigation of bulk single-crystal Sr0.94Ir0.78O2.68 or Ir-deficient, orthorhombic perovskite SrIrO3. It retains the same crystal structure as stoichiometric SrIrO3 but exhibits a sharp, simultaneous antiferromagnetic (AFM) and metal-insulator (MI) transition occurring in the basal-plane resistivity at 185 K. Above it, the basal-plane resistivity features an extended regime of almost linear temperature dependence up to 800 K but the strong …
Anisotropic Softening Of Magnetic Excitations In Lightly Electron-Doped Sr2Iro4, X. Liu, M. P. M. Dean, Z. Y. Meng, M. H. Upton, T. Qi, T. Gog, Y. Cao, J. Q. Lin, D. Meyers, H. Ding, Gang Cao, J. P. Hill
Anisotropic Softening Of Magnetic Excitations In Lightly Electron-Doped Sr2Iro4, X. Liu, M. P. M. Dean, Z. Y. Meng, M. H. Upton, T. Qi, T. Gog, Y. Cao, J. Q. Lin, D. Meyers, H. Ding, Gang Cao, J. P. Hill
Center for Advanced Materials Faculty Publications
The magnetic excitations in electron-doped (Sr1−xLax)2IrO4 with x = 0.03 were measured using resonant inelastic x-ray scattering at the Ir L3 edge. Although much broadened, well defined dispersive magnetic excitations were observed. Comparing with the magnetic dispersion from the undoped compound, the evolution of the magnetic excitations upon doping is highly anisotropic. Along the antinodal direction, the dispersion is almost intact. On the other hand, the magnetic excitations along the nodal direction show significant softening. These results establish the presence of strong magnetic correlations in electron-doped (Sr1−xLax …
Magnetic And Crystal Structures Of Sr2Iro4: A Neutron Diffraction Study, Feng Ye, Songxue Chi, Bryan C. Chakoumakos, Jaime A. Fernandez-Baca, Tongfei Qi, Gang Cao
Magnetic And Crystal Structures Of Sr2Iro4: A Neutron Diffraction Study, Feng Ye, Songxue Chi, Bryan C. Chakoumakos, Jaime A. Fernandez-Baca, Tongfei Qi, Gang Cao
Center for Advanced Materials Faculty Publications
We report a single-crystal neutron diffraction study of the layered Sr2IrO4. This work unambiguously determines the magnetic structure of the system and reveals that the spin orientation rigidly tracks the staggered rotation of the IrO6 octahedra in Sr2IrO4. The long-range antiferromagnetic order has a canted spin configuration with an ordered moment of 0.208(3) μB/Ir site within the basal plane; a detailed examination of the spin canting yields 0.202(3) and 0.049(2) μB/site for the a axis and the b axis, respectively. It is intriguing that forbidden nuclear reflections …