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Full-Text Articles in Physics

Intercalation And High-Pressure Investigations Of Black Arsenic Phosphorus: Unraveling Material Transformations., Dinushika Vithanage Aug 2023

Intercalation And High-Pressure Investigations Of Black Arsenic Phosphorus: Unraveling Material Transformations., Dinushika Vithanage

Electronic Theses and Dissertations

Black arsenic phosphorus (b-AsyP1-y) alloys have emerged as intriguing materials within the realm of two-dimensional (2D) materials, following the discovery of black phosphorus (BP). These alloys possess capability to overcome major limitations of BP and exhibit potential for tunability and enhancement of properties making them promising materials for a wide range of applications, including lithium-ion batteries. Inspired by the intriguing findings obtained for BP, this research focuses on understanding the structural modifications that can be achieved in b-AsyP1-y alloys through the application of intercalation and high pressure. The initial phase of our investigation …


Super P-Sulfur Cathodes For Quasi-Solid-State Lithium-Sulfur-Batteries., Milinda Bharatha Kalutara Koralalage May 2023

Super P-Sulfur Cathodes For Quasi-Solid-State Lithium-Sulfur-Batteries., Milinda Bharatha Kalutara Koralalage

Electronic Theses and Dissertations

Lithium-Sulfur (Li-S) batteries have become a promising candidate to meet the current energy storage demand, with its natural abundance of materials, high theoretical capacity of 1672 mAhg-1, high energy density of 2600 Whkg-1, low cost and lower environmental impact. Sulfide based solid state electrolytes (SSEs) have received greater attention due to their higher ionic conductivity, compatible interface with sulfur-based cathodes, and lower grain boundary resistance. However, the interface between SSEs and cathodes has become a challenge in all solid-state Li-S batteries due to the rigidity of the participating surfaces. A hybrid electrolyte containing SSE coupled with a small amount of …