Physics Commons^™

Coexistence Of Ferromagnetism And Unconventional Spin-Glass Freezing In The Site-Disordered Kagome Ferrite Srsn2Fe4O11, L. Shlyk, S. Strobel, Barry Farmer, Lance E. De Long, R. Niewa

Physics and Astronomy Faculty Publications

Single-crystal x-ray diffraction refinements indicate SrSn₂Fe₄O₁₁ crystallizes in the hexagonal R-type ferrite structure with noncentrosymmetric space group P6₃mc and lattice parameters a = 5.9541(2)Å, c = 13.5761(5)Å, Z = 2 (R(F) = 0.034). Octahedrally coordinated 2a [M(1) and M(1a)] and 6c sites [M(2)] have random, mixed occupation by Sn and Fe; whereas the tetrahedrally coordinated 2b sites [Fe(3) and Fe(3a)] are exclusively occupied by Fe, whose displacement from the ideal position with trigonal-bipyramidal coordination causes the loss of inversion symmetry. …