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Chemistry

Missouri University of Science and Technology

Series

1988

Articles 1 - 3 of 3

Full-Text Articles in Physics

A Mössbauer Effect Study Of Y₂Fe₁₄B And Its Aluminum Solid Solutions, Dwayne E. Tharp, Gary J. Long, Oran Allan Pringle, Gaya Kanishka Marasinghe, William Joseph James, Fernande Grandjean Nov 1988

A Mössbauer Effect Study Of Y₂Fe₁₄B And Its Aluminum Solid Solutions, Dwayne E. Tharp, Gary J. Long, Oran Allan Pringle, Gaya Kanishka Marasinghe, William Joseph James, Fernande Grandjean

Chemistry Faculty Research & Creative Works

The Mössbauer spectra of Y2Fe14B have been measured from 85 to 296 K. Analysis of the spectra indicates that the near-neighbor rare-earth atoms directly influence the orientation of the principal axis of the electric field gradient. The hyperfine parameters are very similar to those of Nd2Fe14B, but the internal fields are somewhat smaller at room temperature in the yttrium compound. The Mösssbauer spectra of Y2(Fe1-xAlx) 14B, where x equals 0.00, 0.02, 0.04, 0.06, and 0.08, have been measured at 85 K. The average internal hyperfine …


A Neutron Diffraction And Mössbauer Spectral Study Of The Structure And Magnetic Properties Of The Y₂Fe₁₄₋ₓsiₓb Solid Solutions, Gaya Kanishka Marasinghe, Oran Allan Pringle, Gary J. Long, William B. Yelon, Fernande Grandjean Nov 1988

A Neutron Diffraction And Mössbauer Spectral Study Of The Structure And Magnetic Properties Of The Y₂Fe₁₄₋ₓsiₓb Solid Solutions, Gaya Kanishka Marasinghe, Oran Allan Pringle, Gary J. Long, William B. Yelon, Fernande Grandjean

Physics Faculty Research & Creative Works

A neutron diffraction and Mössbauer spectral study of Y2Fe14-xSixB shows that silicon preferentially occupies the 4c, and to a lesser extent, the 8j1 sites in Y2Fe14-xSixB. The trend in the site occupancy is the same as in Nd2Fe14-xSixB. The Curie temperature of Y2Fe14-xSixB increases with increasing silicon content. Neutron diffraction data show that the increase in Curie temperature is accompanied by a contraction of the unit cell. Wigner-Seitz cell calculations, using the Y2Fe …


Projectile-Charge Dependence Of Ejected-Electron Spectra, V. D. Irby, Timothy James Gay, Jimmie Garwin Edwards, Edward Boyd Hale, M. L. Mckenzie, Ronald E. Olson Jan 1988

Projectile-Charge Dependence Of Ejected-Electron Spectra, V. D. Irby, Timothy James Gay, Jimmie Garwin Edwards, Edward Boyd Hale, M. L. Mckenzie, Ronald E. Olson

Physics Faculty Research & Creative Works

We have studied H++He and He++3+He ionizing collisions at intermediate energies (60 to 120 keV/amu) and have observed a significant shift in the velocity position of the maxima in forward-ejected electron spectra when changing projectiles from protons to particles. In ionizing collisions, a large portion of the ejected electrons are stranded near the transitory equiforce, or saddle point, position between the target ion and receding projectile. The shift in the electron spectra maxima to smaller velocities, due to changing projectiles from protons to particles, is consistent with the shift in the saddle-point velocity when the projectile …