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The Effects Of Low Doses (1 To 500 Kilograys) Of 100-Kev Electrons On Four Polymers, Cynthia Anne Bradbury
The Effects Of Low Doses (1 To 500 Kilograys) Of 100-Kev Electrons On Four Polymers, Cynthia Anne Bradbury
Physics Theses & Dissertations
Commercial films of polyetherimide (PEI), polyetheretherimide (PEEI), polyethylene terephthalate (PET), and polycarbonate (PC) were exposed in vacuum to l 00-keV electron radiation to total absorbed doses of l, l 0, l 00, 300, and 500 kilograys. The concentration of radiation-generated radicals, as measured by electron paramagnetic resonance (EPR), increased by over an order of magnitude in all four polymers. Correspondingly, the intensity of the infrared absorption peaks increased uniformly for all doses. Solubility tests resulted in decreased solubility in all polymers. IR, EPR, and solubility suggest dehydrogenation of the aliphatic C-H and phenyl C-H sites. The data indicated that cross …