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Atomic, Molecular and Optical Physics

William & Mary

1992

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Formation And Desorption Of Negative Ions From Metal Surfaces, Douglas Hugh Baker Jan 1992

Formation And Desorption Of Negative Ions From Metal Surfaces, Douglas Hugh Baker

Dissertations, Theses, and Masters Projects

Investigations of negative ion and electron emission from gas-covered metal surfaces due to the impact of low energy (30-300 eV) positive ions and, separately, photons (2-5 eV) are presented. In both cases, the negative ion formation process is thought to occur via electron tunneling from the surface or its substrate to a sputtered or photodesorbed neutral atom or molecule.;In particular, absolute total negative ion and electron yields for collisions of positive alkali ions with a gas-covered Mo substrate have been measured. Mass analysis of the sputtered negative ions show that O{dollar}\sb2\sp-{dollar} is the dominant ion at low impact energies. This …