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Full-Text Articles in Physics

Spectroscopy Of Atmospheres, Randika Dodangodage Apr 2024

Spectroscopy Of Atmospheres, Randika Dodangodage

Physics Theses & Dissertations

Spectroscopic methods are used to study planetary and stellar atmospheres. The information obtained from spectroscopic studies provides insight into atmospheric compositions and dynamics, which can be used to model and characterize atmospheres and climates. Laboratory-recorded absorption cross-sections are needed to interpret the recorded spectra of planets and stars. High resolution ethane, neopentane, propene, and n-butane spectra have been recorded, and absorption cross-sections have been provided for different temperatures and total pressures with different broadening gases, including hydrogen, helium, and nitrogen. The Atmospheric Chemistry Experiment (ACE) satellite orbits Earth and records spectra through solar occultation limb observations. HOCl is a chlorine …


Spectra Of Atmospheric And Astronomical Molecules, W. D. Cameron May 2023

Spectra Of Atmospheric And Astronomical Molecules, W. D. Cameron

Physics Theses & Dissertations

Spectroscopy techniques are focused on spectra of molecules of interest to the Earth’s atmosphere and/or astronomy and astrophysics. Laboratory spectroscopy as well as remote satellite sensing are applied. Using the Fourier transform spectrometer aboard the Atmospheric Chemistry Experiment (ACE) satellite to measure the absorption spectra of the Earth’s atmosphere through solar occultation limb observation demonstrates that volcanic eruption plumes can be located and tracked through their SO2 content. The presence of those plumes is corroborated by overlaying infrared atmospheric aerosol extinction observed by the 1 μm imager on the same satellite. Tracking atmospheric aerosol movement with the ACE …


Trend Analyses Of The Abundances Of Atmospheric Molecules, Anton Fernando Apr 2020

Trend Analyses Of The Abundances Of Atmospheric Molecules, Anton Fernando

Physics Theses & Dissertations

A new line list for the A3Π - X3Σ- electronic transition of NH has been prepared using line positions from the literature and calculated line intensities. High level ab initio calculations were performed with the MOLPRO program to obtain the A - X transition dipole moment function. Potential energy curves and line strengths were calculated with Le Roy's RKR1 and LEVEL programs. Line intensities and Einstein A values were calculated with Western's PGOPHER program after converting the Hund's case (b) output of LEVEL to Hund's case (a) input needed for PGOPHER. The Herman- Wallis effect is …


Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv Apr 2003

Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv

Physics Theses & Dissertations

The reaction rate coefficients between the hydronium ion and the molecules ethene (C2H4), propene (C3H6), 1-butene (C4H8) and hydrogen sulfide (H2S) were measured at 296 K. The measured reaction rates were compared to collision rates calculated using average dipole orientation (ADO) theory. Reaction efficiency depends primarily upon the proton affinity of the molecules. All the measurements were obtained using the newly developed microwave cavity discharge flowing afterglow (MCD-FA) apparatus. This device uses an Asmussen-type microwave cavity discharge ion source that is …