Environmental Sciences Commons^™

Technology Platform For Sampling Water With Electrolyte-Gated Organic Transistors Sensitised With Langmuiur-Deposited Calixarene Surface Layers., Delia Puzzovio, Abdullah Al Naim, Lee Hague, Mary Deasy, James P. Ward, Tim Richardson, Martin Grell

Articles

We demonstrate a technology platform that enables the development of new, surface-sensitised organic transistor sensors. We show that an organic semiconductor can still be gated by an electric double layer within the electrochemical window of water after the deposition of up to four Langmuir- Schäfer calixarene layers onto its surface. Since many calixarenes are known to selectively bind waterborne cations, this facilitates sensitising a conventional organic semiconductor with a physically deposited layer for specific cation recognition. When at least two Langmuir-Schäfer layers are deposited, these also block the electrochemical doping of the organic semiconductor, which otherwise competes with the field …